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À propos de : Conformationally Locked Bridged Bicyclic Diselenides: Synthesis,Structure, Se···O Interaction, and Theoretical Studies        

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  • Conformationally Locked Bridged Bicyclic Diselenides: Synthesis,Structure, Se···O Interaction, and Theoretical Studies
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  • A general synthetic methodology has been developed for the synthesis of a conformationally locked,bridged diselena-bicyclo[3.2.1]octane skeleton by regio- and stereospecific tandem nucleophilic ringopening of cis-1,4-aziridino-epoxides with tetraethylammonium tetraselenotungstate [Et4N]2WSe4, 1, ina one-pot synthesis. Some correlations have been made on the physicochemical characteristics of thediselenides with a change in the dihedral angles.
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