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À propos de : Stereoselective Formal Total Synthesis of(+)-Methynolide        

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  • Stereoselective Formal Total Synthesis of(+)-Methynolide
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  • A highly stereoselective and convergent formal total synthesis of (+)-methynolide is described. The salient featuresof this synthesis have been the construction of the C1−C7and C8−C11fragments via a desymmetrization approach,Sharpless asymmetric epoxidation of an allyl alcohol,respectively, and linkage of both the fragments by Nozaki−Hiyama−Kishi reaction.
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