Documentation scienceplus.abes.fr version Bêta

À propos de : Regiochemistry of Copper(I)-MediatedCyclization Reactions of Halo-dienamides        

AttributsValeurs
type
Is Part Of
Subject
Title
  • Regiochemistry of Copper(I)-MediatedCyclization Reactions of Halo-dienamides
has manifestation of work
related by
Author
Abstract
  • Reaction of 2-substituted dienamides with catalytic amountsof copper halide/tripyridylamine (TPA) furnishes either 5-exoor 6-endo products with the outcome dependent upon theradical initiating unit. Reaction of 3-substituted dienamidesproduces β-lactams via a 4-exo cyclization with terminationof the reaction occurring via either halogen atom transfer,trapping with oxygen, elimination, or radical−radical coupling depending upon the diene.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata