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À propos de : Selective Ring Expansion Alkylation ofFormyl[2.2.1]bicyclic Carbinols withC-Nucleophiles: A Unique Route to CyclopentaneDerivatives        

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  • Selective Ring Expansion Alkylation ofFormyl[2.2.1]bicyclic Carbinols withC-Nucleophiles: A Unique Route to CyclopentaneDerivatives
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  • Reactions of camphor-, and camphene-derived formyl [2.2.1]bicyclic carbinols with Grignard and organolithium reagentsafford the corresponding regio- and stereospecific alkyl/aryl[3.2.1]bicyclic diols. Some of these bicyclic diols have beentreated with lead tetraacetate to provide new chiral cyclopentane derivatives. A plausible mechanism of the ringexpansion-alkylation reaction is proposed.
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