About: Air-Stable Racemization Catalysts for the Dynamic KineticResolution of Secondary Alcohols

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/w
Subject	Article
Title	Air-Stable Racemization Catalysts for the Dynamic KineticResolution of Secondary Alcohols
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/m/print http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/authorship/3 http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/authorship/2 http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071065o/authorship/4
Author	Baburaj Baskar Kim Mahn-Joo Park Jaiwook Ko Soo-Byung
Abstract	The substitution of a carbonyl ligand with PPh3 in cyclopentadienylruthenium dicarbonyl complexesproduces a new class of recyclable alcohol racemization catalysts. The catalysts are active at roomtemperature under aerobic conditions in the presence of silver oxide. Furthermore, the catalysts arecompatible with the use of a lipase and isopropenyl acetate for the dynamic kinetic resolution (DKR) ofsecondary alcohols under ambient conditions.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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