About: Lewis Acid-Promoted Conjugate Addition ofDienol Silyl Ethers to Nitroalkenes: Synthesis of3-Substituted Azepanes

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/w
Subject	Note
Title	Lewis Acid-Promoted Conjugate Addition ofDienol Silyl Ethers to Nitroalkenes: Synthesis of3-Substituted Azepanes
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071126i/m/print http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071126i/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071126i/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_18/101021jo071126i/authorship/2
Author	Xie Min Denmark Scott E.
Abstract	A novel γ-selective conjugate addition of 1-silyl-substituteddienol ethers to nitroalkenes activated by Lewis acids hasbeen developed. The resulting α,β-unsaturated acylsilanesundergo photoinduced protodesilylation to afford the corresponding enals, which can be conveniently transformed intoazepanes under appropriate reductive conditions.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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