Documentation scienceplus.abes.fr version Bêta

À propos de : Tandem Oxidation/Halogenation of Aryl AllylicAlcohols under Moffatt−Swern Conditions        

AttributsValeurs
type
Is Part Of
Subject
Title
  • Tandem Oxidation/Halogenation of Aryl AllylicAlcohols under Moffatt−Swern Conditions
has manifestation of work
related by
Author
Abstract
  • Aryl allylic alcohols are converted to halogenated unsaturatedketones or allylic halides using excess Moffatt−Swernreagent. Electron-poor aromatic rings favor formation of thehalogenated ketone, while electron-donating substituents inthe ortho or para positions favor formation of the allylichalide. The oxidation/halogenation reaction performs wellwith both oxalyl chloride and oxalyl bromide, providingaccess to the corresponding chlorides or bromides, respectively.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata