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À propos de : New Preparation of 1,2,4,5,7,8-Hexaoxonanes        

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  • New Preparation of 1,2,4,5,7,8-Hexaoxonanes
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  • A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on theLewis acid catalyzed reaction of acetals with 1,1‘-dihydroperoxydicycloalkyl peroxides. The proceduresubstantially extends the structural diversity of these compounds and, in most cases, allows the synthesisof these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonanewith chloroform was documented for the first time. The structures of several triperoxides were establishedby X-ray diffraction.
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