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À propos de : Aza-Prins-Pinacol Approach to 7-Azabicyclo[2.2.1]heptanes: Syntheses of (±)-Epibatidine and (±)-Epiboxidine        

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  • Aza-Prins-Pinacol Approach to 7-Azabicyclo[2.2.1]heptanes: Syntheses of (±)-Epibatidine and (±)-Epiboxidine
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  • The syntheses of (±)-epibatidine and (±)-epiboxidine have been accomplished from commercial2-methoxy-3,4-dihydro-2H-pyran. A recently developed aza-Prins-pinacol rearrangement was employedfor the construction of the key 7-azabicyclo[2.2.1]heptane skeleton of these targets.
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