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À propos de : Fast Catalytic Epoxidation with H2O2 and[γ-SiW10O36(PhPO)2]4- in Ionic Liquids underMicrowave Irradiation        

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  • Fast Catalytic Epoxidation with H2O2 and[γ-SiW10O36(PhPO)2]4- in Ionic Liquids underMicrowave Irradiation
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  • Olefin epoxidation by [γ-SiW10O36(PhPO)2]4- and H2O2occurs in hydrophobic ionic liquids (ILs), with yields andselectivity up to >99%. The catalytic IL phase is recyclable.Under MW irradiation the reaction occurs with up to 200turnovers per minute. Simultaneous cooling is instrumentalfor quantitative H2O2 conversion.
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