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À propos de : Stereoselective Synthesis of (E)- and (Z)-FluoroalkenylboronatesUsing 2-Fluoroalkylideneiodonium Ylides Generated from(2-Fluoro-1-alkenyl)iodonium Salts        

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  • Stereoselective Synthesis of (E)- and (Z)-FluoroalkenylboronatesUsing 2-Fluoroalkylideneiodonium Ylides Generated from(2-Fluoro-1-alkenyl)iodonium Salts
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  • (E)- and (Z)-(fluoroalkenyl)boronates were prepared stereospecifically by the reaction of 2-fluoroalkylideneiodonium ylide generated from (E)- or (Z)-(2-fluoroalkenyl)iodonium salts with di(p-fluorophenoxy)alkylboranes, followed by transesterification to pinacol esters. The resulting pinacol esters of(fluoroalkenyl)boranes were used for the stereoselective synthesis of trisubstituted fluoroalkenes by cross-coupling reactions.
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