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À propos de : Rhodium-Catalyzed Synthesis of Eight-Membered Rings        

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  • Rhodium-Catalyzed Synthesis of Eight-Membered Rings
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  • Experiments to develop a rhodium catalyst for the [4 + 2 + 2] cycloisomerization of dienynes with asecond alkyne are described. The generality of the reaction is probed in terms of dienyne structure andalkyne structure. A catalyst system that provides cyclooctatrienes in greater than 70% yield is reported.Several experiments to determine the nature of the catalyst are described.
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