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À propos de : Synthetic and Mechanistic Studies of Indium-Mediated Allylation ofImines in Ionic Liquids        

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  • Synthetic and Mechanistic Studies of Indium-Mediated Allylation ofImines in Ionic Liquids
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  • Aldimines derived from aryl and non-enolizable aliphatic aldehydes were allylated with allyl bromidemediated by indium powder in [bpy][BF4] (bpy = N-butylpyridine) to give good yields of the correspondinghomoallylic amines. Selective formation of monoallylated amines can be achieved by varying the amountof bromide ion additive in the form of [bpy][Br]. The transient organoindium intermediates, allylindium(I) and allylindium(III) dibromide formed in the reaction, were studied by NMR spectroscopy to explainthe selectivity.
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