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À propos de : Strained Azetidinium Ylides: New Reagentsfor Cyclopropanation        

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  • Strained Azetidinium Ylides: New Reagentsfor Cyclopropanation
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  • Azetidinium ylides showed a remarkable ability to performthe cyclopropanation of Michael acceptors. Ephedrine-derived azetidinium ylides allowed the formation of substituted cyclopropanes in good yields and at a high level ofstereoselectivity. The determination of the relative stereochemistries in the produced cyclopropanes gave someinsight into the reaction mechanism.
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