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À propos de : Total Synthesis of (±)-Herbindole A, (±)-Herbindole B, and(±)-cis-Trikentrin A        

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  • Total Synthesis of (±)-Herbindole A, (±)-Herbindole B, and(±)-cis-Trikentrin A
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  • Herein we describe a divergent total synthesis of the title compounds utilizing Diels−Alder reactions ofmonoimine quinoids, followed by cyclization of the aromatized adducts to generate the tricyclic skeletons.Elaboration to iodinated or triflated indole derivatives allows for installation of the requisite alkylsubstitution via cross-coupling reactions.
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