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À propos de : Rapid Synthesis of Cyclodepsipeptides Containinga Sugar Amino Acid or a Sugar Amino Alcoholby a Sequence of a Multicomponent Reaction andAcid-Mediated Macrocyclization        

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  • Rapid Synthesis of Cyclodepsipeptides Containinga Sugar Amino Acid or a Sugar Amino Alcoholby a Sequence of a Multicomponent Reaction andAcid-Mediated Macrocyclization
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  • Cyclodepsipeptides incorporating a sugar amino acid (alcohol) have been synthesized. A three-component reaction ofa sugar amino acid (SAA) derivative, an aldehyde, and adipeptide isonitrile in refluxing methanol afforded thecorresponding 5-aminooxazole which, after saponification,underwent a trifluoroacetic acid promoted macrocyclizationto furnish the cyclic sugar amino acids.
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