About: Catalytic Multicomponent Reactions for theSynthesis of N-Aryl Trisubstituted Pyrroles

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_5/w
Subject	Note
Title	Catalytic Multicomponent Reactions for theSynthesis of N-Aryl Trisubstituted Pyrroles
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_5/101021jo0624086/m/print http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_5/101021jo0624086/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_5/101021jo0624086/authorship/2 http://hub.abes.fr/acs/periodical/joceah/2007/volume_72/issue_5/101021jo0624086/authorship/1
Author	Galliford Chris V. Scheidt Karl A.
Abstract	Dirhodium(II) salts efficiently catalyze the three-componentassembly reaction of an imine, diazoacetonitrile (DAN), andan activated alkynyl coupling partner to form substituted 1,2-diarylpyrroles in moderate to good yields. The transition-metal-catalyzed decomposition of the diazo compound in thepresence of the imine presumably generates a transientazomethine ylide that undergoes cycloaddition with dipolarophiles in a highly convergent manner.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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