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À propos de : Efficient Synthesis of Tricyclic Benzobisoxazinesby Silica Gel Catalysis        

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  • Efficient Synthesis of Tricyclic Benzobisoxazinesby Silica Gel Catalysis
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  • A new method for the synthesis of tricyclic benzobisoxazines,based upon silica gel-catalyzed formation of two 3,1-oxazinerings, is reported. The reversibility of the condensationreaction, forming an oxazine ring, allows for implementationof silica gel catalyzed ketone exchange in benzobisoxazine,thus enabling access to nonsymmetric derivatives of benzobisoxazines.
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