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| - Syntheses and Applications of 2-Phosphino-2‘-alkoxy-1,1‘-binaphthylLigands. Development of a Working Model for AsymmetricInduction in Hydrovinylation Reactions
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| - Among the handful of monophosphine ligands that effect asymmetric hydrovinylation of vinylarenes,2-diphenylphosphino-2‘-methoxy-1,1‘-binaphthyl (MOP) is among the most accessible. Addition of amethyl group at the 3‘-position of this ligand significantly improves the enantioselectivity of hydrovinylationof prototypical alkenes. Introduction of a chiral phospholane at the C2 position of this scaffolding has noeffect on the enantioselectivity. These results are consistent with a model proposed for the asymmetricinduction for this exacting reaction.
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