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À propos de : Regioselective Palladium-Catalyzed FormateReduction of N-Heterocyclic Allylic Acetates        

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  • Regioselective Palladium-Catalyzed FormateReduction of N-Heterocyclic Allylic Acetates
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  • The regioselective palladium-catalyzed formate reduction ofallylic acetates in five- to eight-membered heterocycles isreported. Reduction of allylic acetates under mild conditionsusing allylpalladium chloride dimer, phosphines, and formicacid/triethylamine in DMF gives the exo-cyclic olefins ingood regioselectivities and high yields. Synthetic applicationin preparing N-tosyl-3-oxo-piperidine is also reported.
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