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À propos de : Trifluoromethylation of Alkenyl Bromides andIodides (Including 5-Iodouracils) with (CF3)2Hgand Cu (“Trifluoromethylcopper”)1        

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  • Trifluoromethylation of Alkenyl Bromides andIodides (Including 5-Iodouracils) with (CF3)2Hgand Cu (“Trifluoromethylcopper”)1
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  • Bromo- and iodoalkenes undergo trifluoromethylation efficiently in DMA with “CF3Cu” generated from (CF3)2Hgand Cu. Variable stereochemical inversion is observed withsubstrates having a gem-carbonyl group. Substrates havinggem-hydrogen, -alkyl, or -alkenyl groups give products withstereochemical retention.
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