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À propos de : Synthesis of Optically Active Bifunctional Building Blocks throughEnantioselective Copper-Catalyzed Allylic Alkylation UsingGrignard Reagents        

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  • Synthesis of Optically Active Bifunctional Building Blocks throughEnantioselective Copper-Catalyzed Allylic Alkylation UsingGrignard Reagents
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  • Enantioselective copper-catalyzed allylic alkylations were performed on allylic bromides with a protectedhydroxyl or amine functional group using several Grignard reagents and Taniaphos L1 as a ligand. Theterminal olefin moiety in the products was transformed into various functional groups without racemization,providing facile access to a variety of versatile bifunctional chiral building blocks.
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