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À propos de : Synthesis of α-Phosphorylated α,β-UnsaturatedImines and Their Selective Reduction toVinylogous and Saturated α-Aminophosphonates        

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  • Synthesis of α-Phosphorylated α,β-UnsaturatedImines and Their Selective Reduction toVinylogous and Saturated α-Aminophosphonates
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  • An efficient synthesis of α,β-unsaturated imines derived fromα-aminophosphonates is achieved through aza-Wittig reaction of P-trimethyl phosphazenes with β,γ-unsaturated α-ketophosphonates. Selective 1,2-reduction of such 1-azadienesaffords β,γ-unsaturated α-aminophosphonates, phosphorylated analogs of vinylglycines, which are hydrogenated toyield saturated α-aminophosphonate derivatives.
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