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À propos de : Polyhydroxylated Indolines and Oxindoles fromC-Glycosides via Sequential Henry Reaction,Michael Addition, and Reductive Amination/Amidation        

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  • Polyhydroxylated Indolines and Oxindoles fromC-Glycosides via Sequential Henry Reaction,Michael Addition, and Reductive Amination/Amidation
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  • 6-Nitro-2‘-carbonyl-C-glycofuranosides synthesized via Henryreaction from 1-C-allyl 5-aldo-C-glycoside underwent anintramolecular Michael addition to afford nitrocyclohexanolderivatives in good to excellent yield. Reduction of the nitrogroup followed by intramolecular amination with ketone andaldehyde and amidation with ester produced indoline andoxindole derivatives, respectively, in excellent yield.
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