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| Title
| - Structural Studies on Cycloadducts of Furan, 2-Methoxyfuran, and5-Trimethylsilylcyclopentadiene with Maleic Anhydride andN-Methylmaleimide
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| Abstract
| - The early stages of the retro-Diels−Alder reaction are clearly apparent in the structures of the cycloadductsformed between furan or 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methylmaleimide.The degree of lengthening of the C−C bonds that break in this reaction is clearly related to the knownreactivity of these cycloadducts toward this reaction. In the structures of the cycloadducts 21 and 22derived from 2-methoxyfuran, the early stages of an alternative fragmentation reaction are apparent,consistent with the reactivity of these compounds in solution.
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