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À propos de : Electrophile-Induced Ether Transfer: Stereoselective Synthesis of 2,6-Disubstituted-3,4-Dihydropyrans        

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  • Electrophile-Induced Ether Transfer: Stereoselective Synthesis of 2,6-Disubstituted-3,4-Dihydropyrans
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  • Stereoselective synthesis of trans-2,6-disubstituted-3,4-dihydropyrans has been achieved from a simple homoallylic alkoxyether via a three-step sequence: electrophile-induced ether transfer, cyclization, and functionalization, which is highlighted by a rare example of Ferrier rearrangement of allylic ether. This methodology was successfully implemented for the asymmetric synthesis of a C7−C17 fragment of swinholide A.
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