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À propos de : Copper(II)−Bis(oxazoline) Catalyzed Asymmetric Diels−Alder Reaction with α′-Arylsulfonyl Enones as Dienophiles        

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  • Copper(II)−Bis(oxazoline) Catalyzed Asymmetric Diels−Alder Reaction with α′-Arylsulfonyl Enones as Dienophiles
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  • α′-Arylsulfonyl enones are efficient bidentate dienophiles for the Cu(II)-bis(oxazoline) catalyzed enantioselective Diels−Alder reaction with a number of dienes, affording the corresponding products with good to high enantiomeric excesses. The resulting products can be alkylated and the sulfone removed, so α′-arylsulfonyl enones can be regarded as surrogates of simple monodentate enones, which are poor dienophiles with this catalytic system.
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