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À propos de : Catalytic Asymmetric Nitroaldol (Henry) Reaction with a Zinc-Fam Catalyst        

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  • Catalytic Asymmetric Nitroaldol (Henry) Reaction with a Zinc-Fam Catalyst
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  • Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, α,β-unsaturated, and heteroaromatic) and α-ketoesters to give the nitroaldol product in up to 97% yield and 91% ee. The chiral ligand can be recovered and recycled without losing its activity.
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