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À propos de : Formation of γ-Lactones through CAN-Mediated Oxidative Cleavage of Hemiketals        

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  • Formation of γ-Lactones through CAN-Mediated Oxidative Cleavage of Hemiketals
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  • The generation of substituted γ-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an α-heteroatom. Formation of the γ-lactone through the oxidative cleavage is used to assign stereochemistry of the aldol reaction and as the final step in a short synthesis of members of the phaseolinic acid family of natural products.
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