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À propos de : Highly Diastereoselective Addition of the LithiumEnolate of α-Diazoacetoacetate to N-SulfinylImines: Enantioselective Synthesis of 2-Oxo and3-Oxo Pyrrolidines        

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  • Highly Diastereoselective Addition of the LithiumEnolate of α-Diazoacetoacetate to N-SulfinylImines: Enantioselective Synthesis of 2-Oxo and3-Oxo Pyrrolidines
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  • The highly enantioselective synthesis of 2-oxo and 3-oxopyrrolidines has been achieved by diastereoselective additionof the lithium enolate of α-diazoacetoacetate to chiralN-sulfinyl imines, followed by photoinduced Wolff rearrangement or Rh(II)-catalyzed intramolecular N−H insertion.
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