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À propos de : Crystallization-Induced Secondary Selection from a Tandem Driven Dynamic Combinatorial Resolution Process        

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  • Crystallization-Induced Secondary Selection from a Tandem Driven Dynamic Combinatorial Resolution Process
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  • Crystallization-induced secondary selection from a tandem driven dynamic combinatorial library is presented. In a one-pot experiment, an initial nitroaldol equilibrium was kinetically driven by a tandem reaction resulting in a subsequent dynamic library of diastereoisomers. This library was then further driven by a phase change, resulting in amplification and isolation of a highly diastereomerically enriched and synthetically interesting isoindolinone.
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