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| - A Spectroscopic and Theoretical Investigation of Charge Transfer Complexes betweenSilver and Nitric Oxide: Infrared Spectra and Density Functional Calculations ofAgNO+,0,- and Agx(NO)y Clusters (x, y = 1, 2) in Solid Argon and Neon
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| - Laser-ablated silver atoms are reacted with nitric oxide, and products are isolated in solid argon and neon.The pseudo-hyponitrite complex Ag(NO)2Ag is the dominant product, with AgNOAg and AgONNO presentin smaller yields. These complexes are shown using density functional theory to include significant chargetransfer from silver but are not as ionic as the analogous alkali metal complexes of nitric oxide. The neutraland ionic mononitrosyls AgNO+, AgNO, and AgNO- are also observed, and qualitative trends in bond lengthsand frequencies in this series are discussed.
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