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À propos de : Laser Excitation Spectra of Large Alkoxy Radicals Containing 5−12 Carbon Atoms        

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  • Laser Excitation Spectra of Large Alkoxy Radicals Containing 5−12 Carbon Atoms
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  • Laser induced fluorescence spectra of nearly 20 jet-cooled alkoxy free radicals, with up to 12 carbon atoms,have been observed. Trends, as a function of the number of carbon atoms, are reported for origin frequencies,and their dependence upon structural isomers are documented. The interpretation of various bands in thespectra, and their rotational contours, in terms of excited-state vibrations and/or different conformations isdiscussed.
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