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| - Infrared Spectrum of the CH3−PtH Complex in Solid Argon Prepared in the Oxidative C−H Insertion of Methane by Laser-Ablated Pt Atoms
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| - Reactions of laser-ablated Pt atoms with CH4 during condensation in excess argon form CH3−PtH through oxidative C−H insertion show and that the late transition-metal atom Pt is an effective methane activation reagent, in agreement with gas phase investigations. Six observed infrared absorptions correlate with the six strongest calculated harmonic frequencies. The computed C−Pt bond length is slightly shorter than those of Pt complexes with large ligands. In addition, the strongest absorption of the CH2PtH2 methylidene is detected.
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