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À propos de : Microscopic Description of the Low-Temperature Anomalies in Silica and Lithium Silicatevia Computer Simulations        

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  • Microscopic Description of the Low-Temperature Anomalies in Silica and Lithium Silicatevia Computer Simulations
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  • Information about the nature of the low-temperature anomalies and in particular the properties of the tunnelingsystems in silica and lithium silica glasses are revealed via computer simulations. The potential energy landscapeof these systems is systematically explored for adjacent pairs of local minima which may act as double-wellpotentials (DWPs) at low temperatures. Three different types of DWPs are distinguished, related to perfectlycoordinated silica, intrinsic silica defects, and extrinsic defects. Their properties such as the spatial extensionand the dipole moment are characterized in detail. Furthermore, the absolute number of tunneling systems,that is, symmetric DWPs, is estimated. The results are compared with dielectric echo, specific heat, andacoustic experiments on Suprasil I and Suprasil W. A semiquantitative agreement for all relevant features isobtained.
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