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| - Applications for Metal−Organic Frameworks (MOFs) as Quantum Dot Semiconductors
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| - The structure of MOF-5 is considered as being constructed of discrete semiconductor Zn4O13 quantum dotsstabilized and interconnected by terephthalate linkers. Terephthalate can absorb light and sensitize thesemiconductor dots. In this way, MOFs exhibit the photocatalytic activity of MOF-5 for the degradation ofphenols. As a photocatalyst, the most remarkable feature of MOF-5 is the observation of reverse shape-selectivity in which large phenolic molecules that cannot access the interior of the micropores are degradedsignificantly faster than those others that can enter into the particle. MOF-5 also exhibits activity as an activecomponent in photovoltaic and electroluminescence cells.
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