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À propos de : Mn-Coordinated Stillbenedicarboxylic Ligand Supramolecule Regulated by the HerringboneReconstruction of Au(111)        

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  • Mn-Coordinated Stillbenedicarboxylic Ligand Supramolecule Regulated by the HerringboneReconstruction of Au(111)
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  • The fabrication of Mn-coordinated metal−organic networks on the reconstructed Au(111) surface wasinvestigated by scanning tunneling microscopy(STM), with stillbenedicarboxylic acid (SDA) as the linkermolecules. Two network phases have been observed, sorted by the geometry of node Mn atoms with a parallelor a perpendicular geometry with regard to the adjacent units. A commensurate ordering of the networkswith the substrate herringbone reconstructions was identified. The periodic alterations of the Mn unit geometrymay provide us with clear evidence of the modulation effects from the substrate reconstructions. A ladderstructure was obtained for a SDA oversaturated surface, which revealed another coordination interaction betweenthe Mn atoms and the SDA molecules.
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