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À propos de : Photoinduced Intramolecular Electron Transfer of Carbazole Trimer-[60]Fullerene Studiedby Laser Flash Photolysis Techniques        

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  • Photoinduced Intramolecular Electron Transfer of Carbazole Trimer-[60]Fullerene Studiedby Laser Flash Photolysis Techniques
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  • Photoinduced intramolecular events of newly synthesized bis(carbazole trimer)-C60 adducts have been studiedby laser flash photolysis techniques in polar and nonpolar solvents. For bis(tert-butyl-substituted carbazoletrimer)-C60 adduct, charge separation takes place via the excited singlet state of the C60 moiety in polar solventsas revealed by the combination of the C60-fluorescence quenching and transient absorptions of the radical ionpair. On the other hand, for bis(nonsubstituted carbazole trimer)-C60 adduct, although charge separation takesplace, the charge recombination is fast because of the lower electron-donor ability.
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