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À propos de : How Stable are the Mg−Mg Bonds in Magnesium (I) Compounds toward Hydrogenation?        

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  • How Stable are the Mg−Mg Bonds in Magnesium (I) Compounds toward Hydrogenation?
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  • DFT calculations show that the Mg(I)−Mg(I) bonded complexes should undergo rapid hydrogenation to form bridged dihydrido complexes. This phenomenon can be understood on the basis of conversion of conventional 2c−2e bonds into 3c−2e bonds that are stronger.
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