| Abstract
| - Theoretical analysis of the stopped-flow fluorescence time-scan method, as applied for studying theexchange dynamics in micelle solutions, is presented on the basis of the stochastic model of solubilization.Different exchange mechanisms are considered with a focus on the collisional one-particle hopping, wherethe exact solution for the experimentally observable relaxation function is obtained, and the fusion−fission. It is emphasized that whatever the mechanism of exchange is, the long-time relaxation rate constantis independent of the initial condition in the stopped-flow mixing.
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