| Abstract
| - The formation of soluble hydrogen-bonding interpolymer complexes between poly(acrylic acid) (PAA) and poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid)-graft-poly(N,N-dimethylacrylamide) (P(AA-co-AMPSA)-g-PDMAM) at pH = 2.0 was studied. A viscometric study showed that in semidilute solution a physicalgel is formed due to the interconnection of the anionic P(AA-co-AMPSA) backbone of the graft copolymer, in atransient network, by means of the complexes formed between the PDMAM side chains of the graft copolymer andPAA. Dynamic and static light scattering measurements, in conjunction with small-angle neutron scattering measurements,suggest the formation of core−shell colloidal nanoparticles in dilute solution, comprised by an insoluble PAA/PDMAM core surrounded by an anionic P(AA-co-AMPSA) corona. Even if larger clusters are formed in semidilutesolution, the size of the insoluble core remains practically stable. Atomic force microscopy performed under ambientconditions reveal that the particles collapse and flatten upon deposition on a substrate, with dimensions close to theones of the dry hydrophobic core.
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