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À propos de : A Novel Approach for Preparing Single-Layer Molecularly DopedElectroluminescent Polymer Thin Films        

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  • A Novel Approach for Preparing Single-Layer Molecularly DopedElectroluminescent Polymer Thin Films
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  • A single-layer molecularly doped electroluminescent (OEL) polymer thin film has beenprepared via a vapor codeposition process. The presented method may be conveniently applied to manydye-doped polymer thin film systems yet without having to go through existing complicated conventionalsynthesis and fabrication processes. This method, proven in this work to be feasible experimentally,was executed by simultaneously codepositing an EL active dye, a hole-transporting molecule triphenyldiamine derivative (TPD), and two polyimide thin film forming monomers on an indium−tin oxide (ITO)substrate. Carrier injection was provided from an ITO anode and a thermally evaporated aluminumelectrode. Electron−hole recombination and the green light in EL spectra, with an emission maximumat 515 nm, were triggered at a driving voltage of 14 V. Two primary degradation behaviors were identified.First, hydrolysis of the thin films led to the reduction in EL intensity. Second, nonuniform structureformation of the top Al metal in the Al and codeposition film interface caused reduction in the activeemission area and increased the driving voltage required.
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