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Title
| - Analytical Functions for Molecular Weight and Branching Distributionsin Star-, Comb-, and Random-Branched Polymers
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Abstract
| - Long-chain branching has a significant effect on various polymer properties. One of thedetermining molecular parameters is the bivariate distribution of molecular weight and branching density.This work presents analytical distribution functions for three types of branched polymers: random, comb,and star. The primary chains are assumed to have a Schulz−Zimm distribution. It is shown that thedistribution shape strongly depends on the type of branching with polydispersity in the order of star <comb < random.
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