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Nucleophilic attack on the cyclohexadienyl ligand: from mono- to heterobifunctional (cyclohexadiene)iron complexes and the role of the electron-transfer pathway in hydride abstraction
Multiple bonds between main-group elements and transition metals. 67. Synthesis of novel half-sandwich rhenium(V) complexes of mono- and bidentate sulfur-containing ligands: x-ray crystal structure of the xanthate-S,S complex (.eta.5-C5Me5)ReCl3(S2CO-c-C6H11)
Formation of carboxylate complexes from the reactions of carbon dioxide with ethylene complexes of molybdenum and tungsten. X-ray and neutron diffraction studies
Use of palladium-catalyzed coupling reaction in synthesis of homobimetallic dimers: preparation of [bis(cyclopentadienyl)acetylene]metal complexes and their reaction with dicobalt octacarbonyl. Evidence for formation of dihydrido species in diiron complexes
Metalladiboranes of the iron subgroup: K[M(CO)4(.eta.2-B2H5)] (m- iron, ruthenium, osmium) and M'(.eta.5-C5H5) (CO)2(.eta.2-B2H5) (M' = iron, ruthenium). Analogs of metal-olefin complexes
Ligand effects on transition-metal ion reactivity: primary and secondary reactions of cobalt and nickel with alkenes
Reactivity studies of the zirconium-induced insertion of isonitriles into a 1-sila-3-zirconacyclobutane ring. Structural and chemical evidence of carbenium-like intermediates for the intramolecular 1,2-silyl shift and reductive coupling reactions
Clusters containing carbene ligands. A new route to alkyl(dialkylamino)carbene ligands by a novel 1,1-hydrogenation of ynamine ligands
Enthalpy of carbonyl dissociation from metal hexacarbonyls M(CO)6 (M = chromium, molybdenum, tungsten) in alkane solvent: determination of intermolecular agostic bond strengths
Scope and mechanism of oxidative addition of carbon-sulfur double bonds to trinuclear platinum and palladium complexes
Stereoselective syntheses of coordinated secondary and tertiary phosphines. Crystal and molecular structure of [(R*,R*),(R*)]-(.+-.)-[(.eta.5-C5H5){1,2-C6H4(PMePh)2}Fe(PHMePh)]PF6.cntdot.0.5CH2Cl2
(PPh3)3RhCl-catalyzed hydrosilylation of unsaturated molecules by 1,2-bis(dimethylsilyl)ethane: unprecedented rate difference between two silicon-hydrogen bonds
Lithio(diphenylphosphino)methane-tetramethylethylenediamine: crystal structure and NMR studies of a coordinatively unsaturated, monomeric organolithium
A heteroatom-stabilized neutral imine organoactinide complex: x-ray structure of dichlorobis(pentamethylcyclopentadienyl)uranium(IV) phosphine imine
Binuclear diiridium and mixed-metal rhodium-iridium complexes containing terminal .eta.2-alkynes: the structure of [Ir2(CO)(.eta.2-F3CC CF3)(.mu.-S)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.CH2Cl2
Complexes of the allylic diorganotriarsinidene ligand .eta.3-RAsAsAsR. Syntheses and crystal structures of Cp*Mo(CO)2(.eta.3-PhAsAsAsPh) and Cp*W(CO)2(.eta.3-MeAsAsAsMe)
Activation of sp3-carbon-hydrogen bonds in a mono(pentamethylcyclopentadienyl)yttrium complex. X-ray crystal structures and dynamic behavior of Cp*Y(o-C6H4CH2NMe2)2 and Cp*Y[o-C6H4CH2NMe(CH2-.mu.)][.mu.-o-C6H4CH2NMe(CH2-.mu.)]YCp*[THF]
Origin of the distinctly different gas-phase chemistry of linear and .alpha.-branched aliphatic nitriles with bare iron(I) ions. Evidence for oxidative addition of the carbon-cyano bond to iron(+), new mechanisms for the reductive eliminations of alkanes, and a demonstration of consecutive carbon-hydrogen/carbon-carbon bond activations of different sites of flexible molecules
Organotransition metal metallocarboranes. 14. Pyrrolyl-transition metal-carboranyl double-decker and triple-decker sandwich complexes
Preparation, properties, and reactions of metal-containing heterocycles. 65. The behavior of tetracarbonyl(.eta.2-ethene)ruthenium toward activated alkenes and alkynes
Fluxionality of (.eta.2-naphthalene)(iso-Pr2P(CH2)n-iso-Pr2P)Ni0 (n = 2,3) in the solid state and solution as studied by CP/MAS and 2D carbon-13 NMR spectroscopy
Synthesis and structure of chiral rhenium allyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CH2C(R') = CHR)
Bonding in transition-metal-silyl dimers. Molecular orbital theory
Electrochemical synthesis of Costa-type cobalt complexes
Experimental, structural, and theoretical studies of diplatinum complexes containing bridging phenylethenylidene ligands including the excited-state chemistry and photophysics of photochemically generated species
Photolysis of tetracarbonylnickel in dihydrogen-containing matrixes. Evidence for the formation of a complex of molecular hydrogen
Mechanistic studies on the thermal and photochemical decomposition of dimethyl(2,4-pentanedionato)gold(III) in solution
Synthesis and molecular structure of tetramethylbis(.mu.-pyridine-2-thiolato)dialuminum(III), [Me2AlPyS]2: an example of a unique head-to-head bridged pyridine-2-thiolato ligand
Preparation and structure of aluminum derivatives of the extremely bulky tris(trimethylsilyl)silyl group. The molecular structure of the (Me3Si)3SiAl(C6H5)2.cntdot.THF adduct
Masthead
The Hurtley reaction. 1. Synthesis and characterization of copper(I) benzoates containing reactive ortho C-X (X = Cl, Br) bonds and their reactivity toward organocopper(I) compounds: crystal structure of a thermally stable trinuclear hetero copper(I) cluster, bis(benzoato)mesityltricopper(I)
Coordination chemistry of Group 14 metalloles. 5. Use of dicarbonyl(.eta.5-cyclopentadienyl)(1-methyl-2,5-diphenylsilacyclopentadien-1-yl)iron as a four-electron ligand: chemical properties and dynamic stereochemistry of the complexes
An unexpected isotope scrambling process accompanies hydrozirconation of styrene
Studies on the fluxional behavior of the tetrahedro-triosmium-platinum clusters Os3Pt(.mu.-H)2(CO)9(PCy3)(CNCy) and Os3Pt(.mu.-H)2(.mu.-CH2)(CO)9(PCy3)(CNCy) using carbon-13 EXSY. Direct evidence for the rotation of the Pt(H)(PCy3)(CNCy) unit from dynamic osmium-187-hydride coupling constants
Silyl-substituted diphosphenes. Synthesis, structure, and modes of decomposition
Studies on hydrometalation reactions: an improved hydrozirconation reagent and the structure of a (MeCp)2ZrCl(alkenyl) carbonylation product
Deprotonation of the adducts of .beta.-dicarbonyl anions and [(.eta.4-diene)Co(CO)3]BF4
Synthesis and spectroscopic investigations of optically active alkylaluminum compounds of l-ephedrine. The crystal structure of the [cyclic] [Me2Al(O-(R)-CHC6H5(S)-CH((S)-NHCH3)CH3)]2 dimer: an optically active five-coordinate aluminum complex
1,5-Dihydropyrrol-2-ones from (1,4-diaza-1,3-diene)tricarbonyliron, (DAD)Fe(CO)3, and alkyne. 5. Spectroscopic and x-ray structural characterization of a bicyclo[2.2.1] complex resembling the initial cycloadduct. The C = N-Fe fragment in (DAD)Fe(CO)3 as an isolobal analog of the classical 1,3-dipole azomethine ylide in 1,3-dipolar cycloaddition
Coupling versus substitution of coordinated ethylene with iminooxosulfanes: crystal structure of [Os{CH2CH2S(NSO2C6H4Me-4)O}Cl(NO)(PPh3)2]
Reversibility of metal-alkyl intermediate formation in the rhodium-catalyzed deuterioformylation of 1-hexene
Electrochemical differentiation of .alpha.- and .beta.-diastereoisomers of the steroid hormone receptor marker 3-(benzyloxy)-17.beta.-hydroxyestra-1,3,5(10)-trienetricarbonylchromium
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