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New electron-rich chiral phosphines for asymmetric catalysis
Bimetallic macrocyclic zirconocene dialkoxides: synthesis, structure, bonding, and molecular modeling considerations
Spiked-triangular versus puckered-square geometry in 64-electron osmium clusters. Synthesis and structure of Os4(CO)15(L) (L = CO, PF3, P(OCH2)3CMe)
Synthesis and characterization of copper(I) trifluoroacetate alkyne complexes of type Cu4(.mu.-O2CCF3)4(.mu.-alkyne)2 and Cu2(.mu.-O2CCF3)2(alkyne)2
High-resolution solid-state tin-119 and carbon-13 NMR studies of novel organotin(IV) coordination polymers involving R3Sn and M(CN)m fragments
Coupling of alkynes on a cluster core: reaction of Cp'2Mo2Co2(CO)4S3 with alkynes
General synthetic routes to chiral, ethylene-bridged ansa-titanocene dichlorides
Alkylcobalt carbonyls. 10. Carbon monoxide activation and phase-transfer-active coordination sites in organocobalt carbonyls. Mechanism of the reaction of benzyl halides and tetracarbonylcobaltate(I)
Stannadesulfurization of a bis(diethyldithiocarbamato)tungsten(II) complex. Formation of an aminocarbynetungsten complex
Organometallic reactions in aqueous medium. Conversion of carbonyl compounds to 1,3-butadienes or vinyloxiranes
Niobocene chemistry: acetylene hydrido, acetylene alkenyl, and carbenoid butadienyl complexes
Facile conversion of organometallic halide complexes to halomethyl derivatives: synthesis, structure, and reactivity of the (.eta.5-C5R5)Cr(NO)2CH2X series (R = H, CH3; X = Cl, Br, I, OCH3, OCH2CH3, PPh3, CN, SO3C6H4CH3)
Redox behavior of nickel acylate complexes
Novel phosphido-bridged cations [M2(CO)8(.mu.-PPh2)]BF4 (M = iron, ruthenium): synthesis, reactivity, and x-ray structure of an isoelectronic and structural analog of Ru2(CO)9
Synthesis and reactivity of 2-lithio-1,1,3,3-tetramethyl-1,3-disilacyclobutane. Strain-assisted ring-opening processes
.eta.4-Siloles as ligands for cationic cobalt and rhodium phosphine complexes
Heterometallic analogs of [(.eta.5-C5Me5)M(CO)2]2 (M = Fe, Ru, Os). Synthesis and structures of (.eta.5-C5Me5)2(CO)4IrRe, (.eta.5-C5Me5)2(CO)4IrMn, and (.eta.5-C5Me5)(.eta.5-C5H5)(CO)4IrRe
Synthesis and dimerization of 2,3-dimethyl-5-silaspiro[4.4]nona-2,7-diene. Structure determination of 2,3,12,13-tetramethyl-5,10-disiladispiro[4.4.4.4]octadeca-2,7,12,16-tetraene by x-ray crystallography
Rotation of coordinated acetylide ligands on the triangular surface of trinuclear heterometallic clusters
Hydrolysis of tetrachloro(pentamethylcyclopentadienyl)niobium(V). Crystal structure of [Nb2(.eta.5-C5Me5)2Cl2(.mu.2-O)(.mu.-Cl)](.mu.2-O)2(.mu.3-O)[Nb(.eta.5-C5Me5)Cl]
Formation of carbon-hydrogen and oxygen-hydrogen bonds at iridium centers: addition of hydrogen and hydrogen chloride to trans-RIr(CO)L2(R = Me, OMe; L = PPh3, P(p-tolyl)3)
Improved synthesis of (aminocarbene)chromium(0) complexes with use of C8K-generated Cr(CO)52-. Multivariant optimization of an organometallic reaction
Comparative studies on reactions of .alpha.,.beta.- and .beta.,.gamma.-unsaturated amides and acids with nickel(0), palladium(0), and platinum(0) complexes. Preparation of new five- and six-membered nickel- and palladium-containing cyclic amide and ester complexes [Erratum to document cited in CA113(15):132466t]
Synthesis, structures, and conformational dynamics of dicobalt complexes containing the hexafluorodidehydrocyclooctatetraene (hexafluorocycloocta-3,5,7-trien-1-yne) ligand. Crystal and molecular structures of [(Co(L)(CO)2)2(.mu.2-(1.eta.,2.eta.)-C8F6)] (L = CO, PPh3, PPhMe2, PMe3)
Synthesis of (1RS,2RS,5SR)-3,4,6,7-tetramethylidene-8-oxobicyclo[3.2.1]oct-2-yl acetate and the chemo- and stereoselective coordination of its butadiene functions with rhodium and iron moieties
Reactions of [Et3NH][(.mu.-CO)(.mu.-RS)Fe2(CO)6] complexes with acetylenes. Synthesis and decarbonylation of .alpha.,.beta.-unsaturated bridging acyl complexes
Interaction of rhodium(I) with cyclopropenones: decarbonylation and formation of 1-rhodacyclopentene-2,5-diones and cationic oxygen .sigma.-bound cyclopropenone complexes. X-ray crystal structure of trans-carbonylbis(triphenylphosphine)(di-tert-butylcyclopropenone)rhodium trifluoromethanesulfonate
A revisionist view of fluxionality in metal polyhydrides: the role of exchange coupling
Synthesis of dimanganese nonacarbonyl cyclic carbene complexes and molecular structures of two of them
Unexpected reactivity of bifunctional hexacoordinated silicon species
Polyhedral aluminosilsesquioxanes as models for aluminosilicates: unique synthesis of anionic aluminum/silicon/oxygen frameworks
Cyclopentadienylniobium and -molybdenum phosphorodithioate complexes. X-ray crystal structures of CpNbCl3[S2P(OPr-iso)2], CpNbCl(.mu.-Cl)2Nb[S2P(OPr-iso)2]Cp, and cis-Cp'Mo(CO)2[S2P(OPr-iso)2]
Synthesis, structure, and fluxional properties of the cationic rhodium clusters [(.eta.-C5H5)2Rh3(CO)(CF3C2CF3)(CNR)3]+PF6- (R = iso-Pr, tert-Bu). Unexpected attachment of the alkyne in the crystal structure
Structure of a trinuclear dizirconium-aluminum (Zr2Al).mu.-ketone complex with a bridging trigonal-bipyramidal methyl group
Decomposition of .alpha.-phenethylbis(dimethylglyoximato)cobalt(III) complexes. Influence of electronic and steric factors on the kinetics and thermodynamics of cobalt-carbon bond dissociation
Masthead
Chemistry of C-trimethylsilyl-substituted main-group heterocarboranes. 7. Reactivity of closo-germa- and closo-plumbacarboranes toward a bis(bidentate) Lewis base 2,2'-bipyrimidine: syntheses and structures of 1- or 1,1'-(2,2'-C8H6N4)[closo-1-M-2-(Me3Si)-3-(R)-2,3-C2B4H4]n (n = 1, M = Ge; n = 2, M = Pb; R = Me3Si, Me, H)
A new class of silicon compounds with interesting nonlinear optical effects
Transformations of strained-ring thioethers by metal cluster complexes. Nature of the ring opening of a bridging 3,3-dimethylthietane ligand in a triosmium cluster complex
Effect of polyfluorination on ring inversion barriers for cyclooctatetraenes. Transition-metal compounds of unsaturated, polyfluorinated cycloaliphatics. Crystal and molecular structures of [Fe(.eta.-C5R5)(.eta.1-heptafluorocycloocta-1,3,5,7-tetraenyl)(CO)2] (R = H, Me), {[Fe(.eta.-C5H5)(CO)2]2(.mu.2-(1.eta.,5.eta.)-hexafluorocycloocta-1,3,5,7-tetraenediyl)], and [Mn((3.eta.)-heptafluorotricyclo[4.2.0.02,5]octa-3,7-dienyl)(CO)5]
Reactions of the rhenium cyanomethyl complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) and ylide complex [(.eta.5-C5H5)Re(NO)(PPh3)(CH2P(p-tol)3))]+PF6- with n-BuLi/TMEDA: generation, stereospecific alkylation, and basicity of transition-metal-substituted carbanions and ylides
Further studies of imido alkylidene complexes of tungsten, well-characterized olefin metathesis catalysts with controllable activity [Erratum to document cited in CA113(17):152665k]
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