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Carbon-13 CP/MAS NMR spectroscopy of magnesium-anthracene and -cyclooctatetraene complexes: graphite-assisted degradation of a magnesium-anthracene complex
Reactions of di- and polynuclear complexes. 7. Reaction of [cyclic] [(CO)3Co(.mu.-RC2R')Co(CO)3] (R = R' = CF3, CO2Me; R = CF3, C6H5 and R' = H) with [{FeCp(CO)2}2]. Di- and tetranuclear mixed-metal complexes. Alkyne coordination and scission by a tetrametallic framework. Crystal structures of [Co3FeCp(.mu.4-.eta.2-C:CHCF3)(.eta.6-C7H8)(.mu.-CO)2(CO)4] and [Co3FeCp2(.mu.4-.eta.2-C.tplbond.CCF3)(.mu.-CO)(CO)5]
Preparation, properties, and bonding analysis of tantalum(II) .eta.6-arene complexes
Formation and molecular structure of hydridotricarbonyl{[.eta.5-(diphenylphosphino)cyclopentadienyl][.eta.7-(diphenylphosphino)cycloheptatrienyl]titanium-P,P'}manganese: a new chelated titanium-manganese heterobimetallic compound
Aminium salt catalyzed dimerization and cross additions of vinylferrocene
Organometallic complexes with electronic bridges. 6. Novel organometallic complexes containing aromatic azines: synthesis and x-ray crystal structure of 4,6-bis[(.eta.5-cyclopentadienyl)dicarbonyliron] 2-(methylthio)pyrimidine
Pentadienyl-metal-phosphine chemistry. 23. Pentadienyl-iridium-phosphine chemistry. Survey of the reactions of pentadienide reagents with ClIrL3 complexes
.alpha.,.beta.-Unsaturated thioamide and thioester iron tricarbonyls: synthesis, characterization, and novel cycloaddition reactions with alkynes
Unusual mixed-metal carbonate-bridged complexes via oxidation of a carbonyl ligand in [RhM(CO)4(Ph2PCH2PPh2)2] (M = Mn, Re) and [IrRe(CO)5(Ph2PCH2PPh2)2]
Synthesis, structure, and dynamic behavior of rhenium sulfide and sulfoxide complexes of the formula [(.eta.5-C5H5)Re(NO)(L)(XRR')]+X'- (X = S, SO)
Chemistry of iridium carbonyl cluster complexes. Synthesis and characterization of mixed-metal carbonyl clusters via capping reactions with HgCl2 and Au(PPh3)Cl. Crystal structures of [N(PPh3)2][Ir6(.mu.3-CO)3(CO)12(.mu.3-HgCl)].cntdot.0.5C6H12 and [NMe3(CH2Ph)][Ir6(.mu.-CO)3(CO)12[.mu.3-Au(PPh3)].cntdot.C4H8O
Facile syntheses of new incompletely condensed polyhedral oligosilsesquioxanes: [(c-C5H9)7Si7O9(OH)3], [(c-C7H13)7Si7O9(OH)3], and [(c-C7H13)6Si6O7(OH)4]
Multicenter ligand transformations. Hydrogenation with a trans stereochemistry. The synthesis of rhenium complex Re2(CO)8[trans-.mu.-Me(H)C:C(H)NMe2] by the addition of hydrogen to Re2(CO)8(.mu.-MeC.tplbond.CNMe2)
Alkylidyne-alkyne coupling reactions. Reactions of molybdenum-cobalt complex Mo2Co(CO)7Cp2(.mu.3-CH) with EtC2Et and PhC2Ph
Reaction of metal carbonyl anions with metal carbonyl dimers: thermodynamic and kinetic factors that control the reactions
Sulfur-coordinated thiophene and dibenzothiophene in Cp'(CO)2Re(thiophene) complexes
Metal acetylide CpW(CO)3C.tplbond.CPh and hydride CpW(CO)3H complexes as building blocks to prepare tungsten-ruthenium heterometallic clusters. Synthesis, characterization, and crystal structure of CpWRu3(CO)9(.mu.3-COMe)(C:CHPh), Cp2W2Ru3(CO)9[CC(Ph)C(OMe)](C:CHPh), and Cp2W2Ru3(CO)9(COMe)(C.tplbond.CPh)
X-ray crystal structure and theoretical study of tris(2,3-dimethyl-1,3-butadiene)molybdenum(0)
Polydentate ligands containing phosphorus. 14. Synthesis and molecular structure of (1,5-cyclooctadiene)[bis(diphenylphosphinoyl)(diphenylthiophosphinoyl)methanido]rhodium(I) 2-propanol, (COD)Rh{[(O)PPh2]2[(S)PPh2]C}.cntdot.i-PrOH
Formation of organodilithium compounds via lithium-tin exchange
A polyfunctional chromium arene complex: synthesis and derivatization of tricarbonyl(.eta.6-1,4-epoxy-1,2,3,4-tetrahydronaphthalene)chromium(0)
Chemistry of oxophilic transition metals. 4. Reactivity of the organozirconium(III) complex (.mu.-.eta.5:.eta.5-C10H8)[(.mu.-Cl)Zr(.eta.5-C5H5)]2 with diphenyldiazomethane, tert-butyl isocyanide, and trimethylsilyl azide: diazo, cyano, and imido complexes
Cyclometalation of 1-aza-1,3-dienes in reactions with Ru3(CO)12 with formation of four- and five-membered azaruthenacycles
Preparation and carbonylation of ring-functionalized methyl zirconocenes [(.eta.5-C5H4)P(C6H5)2]2Zr(CH3)2-nCln (n = 0, 1). Observation and x-ray structure of a fluxional acyl-phosphonium moiety in the complex [cyclic] [(.eta.5-C5H4)P(C6H5)2][(.eta.5-C5H4)P(C6H5)2Zr[.eta.2-(OC)CH3]Cl
High-field NMR study of vertex rotation in (C5HnMe5-n)MCo2(CO)8CR clusters (M = molybdenum, tungsten): x-ray crystal structure of (C5Me5)MoCo2(CO)8CCO2-iso-Pr
Ultrasonic activation of chalcogen-chalcogen bonds: synthesis of bis(organyltellurenyl) selenides and sulfides, (RTe)2(Se,S)
Transition-metal derivatives of the cyclopentadienylphosphine bridging unit. VI. Oxidation, oxidative addition, insertion, and metal-metal bond formation in dirhodium complexes
Halide-promoted carbon monoxide labilization applied to the synthesis of alkyne-substituted derivatives of Ru3(CO)12
Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactions
Synthesis and properties of novel organozinc enolates of N,N-disubstituted glycine esters. Molecular structure of [cyclic] [EtZnOC(OMe):C(H)N(tert-Bu)Me]4
Synthesis, characterization, and reactivity of (.eta.5-C5H7)V(CO)4 and its phosphine derivatives
Lithium-induced cyclization of tribenzo cyclotriynes
Unexpected synthesis of CpIr(.eta.4-C5H6) and a proton and carbon-13 NMR comparison with its cobalt and rhodium congeners
Direct electrochemical synthesis of X2InCH2X compounds (X = Br, I) and a study of their coordination chemistry
Dehydrogenative coupling reactions to form silazane oligomers promoted by binuclear rhodium complexes
Pentacoordinate hydridosilicates: synthesis and some aspects of their reactivity
Square Fe2Au2 and triangular Fe2Au clusters: A reversible transformation. X-ray crystal structure of [Fe2Au2(CO)8(.mu.-dppm)] [dppm = bis(diphenylphosphino)methane]
Bidentate and tridentate coordination modes of a novel bicyclic ditertiary phosphine ether
Bis(cyclooctatetraenyl)zirconium: x-ray crystal structure and solution and solid-state NMR spectra
One-step, two-electron oxidation of (.eta.5-C5H5)W(CO)3CH3: unexpected formation of stable tungsten(IV) dications
Selective hydrogenation of .alpha.,.beta.-unsaturated aldehydes in aqueous organic two-phase solvent systems using ruthenium or rhodium complexes of sulfonated phosphines
1-Sila-3-metallacyclobutanes, precursors for the generation of highly electrophilic Group 4 metallocene alkyl cations. Spectroscopic and structural evidence of a weakly bound THF ligand in [(C5Me5)2Zr(CH2SiMe3)(THF)][BPh4]
Synthetic equivalents of 2-lithiophosphinines: new routes to 2-functional phosphinines
Masthead
Synthesis of 1,1-di-tert-butylsilirane, the first silirane with no substituents on the ring carbons
Decarboxylation of (triphenylphosphine)gold(I) carboxylates
Acidolysis of rhodium complexes [MeC(CH2PPh2)3]Rh(CH3)n: controlled creation of unsaturation
Binuclear tungsten carbonyls bridged both by hydride and by bidentate phosphine ligands: (.mu.-H)(.mu.-Ph2P(CH2)nPPh2)W2(CO)7(NO) (n = 1-5) and (.mu.-H)(.mu.-(Ph2PCH2)3CMe)W2(CO)7(NO)
Class II mixed-valent complexes from oxidation of doubly linked (arene)chromium compounds
Dialkyl- and chloroalkyltitanium ansa-metallocene complexes: synthesis and characterization. Crystal structure of [.eta.5-.eta.5-(C5H4)2Si(CH3)2]TiClCH3
Assembling ethylene, alkyl, hydride, and carbon monoxide ligands at iridium
Synthesis and characterization of indium-arsenic compounds containing a four-membered [cyclic] In-As-In-As or [cyclic] In-As-In-Cl ring: crystal structures of [(Me3SiCH2)2InAs(SiMe3)2]2 and [cyclic] (Me3SiCH2)2InAs(SiMe3)2In(CH2SiMe3)2Cl
Photochemistry of methyltrioxorhenium(VII)
Low-valent titanium porphyrin complexes. Synthesis and structural characterization of the first titanium(II) porphyrin complex, (.eta.2-diphenylacetylene)titanium octaethylporphyrin
Absence of hydrogen bonding between cobalt carbonyl (HCo(CO)4) and nitrogen or oxygen bases. IR and Raman study
Rhodium-catalyzed carbonylation of acetylenes under water-gas shift reaction conditions. Selective synthesis of furan-2(5H)-ones
A tricyclic ring system of six carbon and five boron atoms from monoalkylbenzene and five formal borene units
Electrochemistry of ruthenium carbonyls
Reactions of (.eta.-C5Me5)Ta(PMe3)(H)2(.eta.2-CHPMe2) and nature of the .eta.2-CHPMe2 ligand
Structure and properties of diestertin(IV) complexes (CH3OOCCH2CH2)2Sn(Ch)Cl (Ch = dimethyldithiocarbamate, dihydrobis(pyrazolyl)borate)
Reactions of cationic ruthenium hydrides with 1-alkynes: formation of .sigma.-alkynyl ruthenium complexes and reduction of 1-alkynes to 1-alkenes
Synthesis and electrophilic destannylation reactions of trimethylstannyl-substituted methyl crotonates
Preparation, reactivity, and x-ray structure of a cationic alkoxyzirconocene complex
Mechanism of the photoreaction between (.eta.5-C5H5)M(CO)3X (M = molybdenum, tungsten) and allylic halides
Unusual rearrangement of [.alpha.-(silylalkyl)alkoxycarbene]tungsten complexes: x-ray crystal structure of (E)-(CO)5W[C(N(CH3)2)CH2CH2CH:C(OCH3)Si(CH3)3]
Synthesis of pure racemic isomers of ansa-titanocene dichlorides: conformational preferences are determined by substitution patterns on the cyclopentadienyl rings
Structural studies on ruthenium carbonyl hydrides. 16. Isomerism in 47- and 48-electron (methylidyne)triruthenium clusters. Crystal structures of (.mu.-H)3Ru3(.mu.3-COMe)(CO)6{.mu.3-(PPh2CH2)3CMe} and (.mu.-H)3Ru3(.mu.3-COMe)(CO)7{.mu.2-(PPh2)3CH}.cntdot.1.25CH2Cl2
Synthesis and fluxional behavior of protonated 1,3-diene complexes of ruthenium(0), osmium(0), rhodium(I), and iridium(I) containing 2,3-dimethylene-5,6,7,8-dibenzobicyclo[2.2.2]octane (ddbo, C18H14). Single-crystal x-ray study of the agostic complex [Ru(C18H15)(.eta.-C6H3Me3)]PF6
New azasilatranes: thermal conversion of unusual azasilatranium pseudohalides to neutral 1-(pseudohalo)azasilatranes
NMR structural and dynamic study of a carbenium ion with a steroidal substituent [Mo2Cp2(CO)4(.mu.-HC:CC19H24O]+BF4-
Organometallic derivatives of diphosphazanes. 2. Seven-coordinated Group 6 metal tricarbonyl complexes of diphosphazane ligands. X-ray crystal structure of [WI2(CO)3{P(OPh)2}2NPh]
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