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issue	8
is Is Part Of of	Effect of molecular shapes on crystal building and dynamic behavior in the solid state: from crystalline arenes to crystalline metal arene complexes Organometallic compounds of the lanthanides. 64. Synthesis and x-ray crystal structures of dimethylgermyl bis(tetramethylcyclopentadienyl) halide and alkyl derivatives of the lanthanides Formation of iron carbonyl complexes of reactive polyenes from dihalides involving the free polyene (Arene)osmium trihydride complexes: synthesis and studies of proton-proton exchange coupling A new catalyst for the epimerization of secondary alcohols: carbon-hydrogen bond activation in the rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR') Photochemical generation of a novel eight-membered-ring silene Organometallic reactions in aqueous media. 2. Convenient synthesis of methylenetetrahydrofurans Electron transfer between mononuclear metal carbonyl anions (M(CO)5-, M = Mn, Re; CpFe(CO)2-; CpM(CO)3-, M = Cr, Mo) and trinuclear clusters (M3(CO)12, M = Fe, Ru, Os) and between trinuclear dianions (M3(CO)112-, M = Fe, Ru, Os) and metal carbonyl dimers (Mn2(CO)10 and Cp2M2(CO)6, M = Cr, Mo, W) Electronic structures of simplified polymeric organosilicon systems containing .pi.-conjugated moieties New photochemical routes to germylenes and germenes and kinetic evidence concerning the germylene-diene addition mechanism Isomerization of a vinylcyclobutene to a cyclohexadiene: a nickel(I) promoted rearrangement Synthesis and characterization of palladium complex trans-(Me3P)2Pd(C6H4C(H):NPr-iso)(NHPh). X-ray crystal structure analysis of [(Me3P)3Pd(C6H4C(H):NPr-iso)][BF4] Phosphorus abstraction reactions related to hydrodesulfurization: formation of Cp'2Mo2Co2S3(CO)2(.mu.3-PR) from Cp'2Mo2Co2S3(CO)4 and phosphines Preparation and properties of (.eta.-C5H5)2TiCl(SeH), (.eta.-C5H5)2Ti(SeH)2, [(.eta.-C5H5)Ti]4(.mu.2-Se)3(.mu.3-Se)3, and related cyclopentadienyl selenides of titanium Chemical and electrochemical oxidation of mer/fac-Cr(CO)3(.eta.1-L-L)(.eta.2-L-L) containing a pendant donor atom: ESR studies of the cations mer-[Cr(CO)3(.eta.1-L-L)(.eta.2-L-L)]+ and trans-[Cr(CO)2(.eta.2-L-L)2]+ (L-L = bidentate group 15 ligand Silicon-carbon unsaturated compounds. 29. Photochemical behavior of 2,6- and 2,7-bis(pentamethyldisilanyl)naphthalene Titanocene(III) phosphides: trapping and structure of mononuclear intermediates in the formation of [Cp2Ti(.mu.-PR2)]2 Metal-.pi.-complexes of benzene derivatives. 37. Redox behavior of the sandwich complexes C12H12M (C12H12 = C6H6 + C6H6, C5H5 + C7H7; M = vanadium, chromium). A comparative study Nucleophile/electrophile double additions to (1-methoxynaphthalene)tricarbonylchromium(O). Application in a formal synthesis of the aklavinone ab ring Carbon-hydrogen bond activation of nitromethane by palladium complex [Pd2Cl2(.mu.-Me2PCH2PMe2)2]: formation and x-ray structure of the face-to-face dimer [Pd2Cl2(CH2NO2)2(.mu.-Me2PCH2PMe2)2] Activation of organomagnesium reagents by crown ethers: unusual ether cleavage of (2-methoxy-1,3-xylylene)-15-crown-4 Organolanthanide-catalyzed dehydrogenative coupling of silanes. Mechanistic implications Metallacarborane complexes as guests for cyclodextrins. Molecular structure of the inclusion complex Cs[closo-3,3,3-(CO)3-3,1,2-ReC2B9H11.cntdot..alpha.-CD].cntdot.8H2O Palladium chloride catalyzed dicarbonylation of terminal alkynes Silicon-carbon unsaturated compounds. 33. Regiochemistry in the photochemical formation of silenes from 1,2,2,2-tetramethyl-, 1,1,2,2-tetramethyl-, and 2-ethyl-1,2,2-trimethylphenylvinyldisilane Incorporation of a complexed hydridoaluminum (AlH) fragment into a metallacycle. Preparation and characterization of CpCoC4Ph4AlH.cntdot.NEt3 Reactions of silenes with .alpha.,.beta.-unsaturated aldehydes and ketones Reaction of 1,3-diphospholyl anions with chlorotrimethylsilane: [1,5]-sigmatropic shifts of the trimethylsilyl group around the 1,3-diphospholyl ring Dehydrogenation of a cyclohexyl group in tricyclohexylphosphine complexes of ruthenium. X-ray crystal structure of [Ru(C6H9PCy2)(CF3COO)]2(.mu.-CF3COO)2(.mu.-OH2) Is the haptotropic rearrangement in bis(tributylphosphine)(anthracene)nickel inter- or intramolecular? Determination of the molecularity by a spin saturation transfer approach Unusual, coordinatively unsaturated rhodium/rhenium and iridium/rhenium, alkyl, acyl, and hydrido complexes. Structure of [RhRe(CH3)(CO)4(Ph2PCH2PPh2)2][CF3SO3].cntdot.3CH2Cl2 Organotransition-metal metallacarboranes. 21. Transition-metal sandwich complexes of heterocyclic ligands. Carborane-stabilized .eta.5-pyrrolyl and .eta.5-phospholyl double-decker and triple-decker compounds: synthesis, structure, and electrochemistry Deuterium substitution of thiophenes by D2: catalytic role of a hydrosulfido-bridged molybdenum complex Activation of 1-alkynes by hexamethylbenzene-ruthenium(II) derivatives. Synthesis and characterization of alkoxyalkylcarbene-ruthenium(II) complexes via highly reactive vinylidene intermediates Reaction of cationic diiron .mu.-(.eta.1:.eta.2)-acetylide complexes [(FP)2(C.tplbond.CR)BF4 (R = H, Ph) with carbon nucleophiles and hydride. Formation of .mu.-vinylidene complexes Trimethylsilyl and related cations in solution Masthead Reactions of silanes with the binuclear hydride [[(Me2CH)2PCH2CH2P(CHMe2)2Rh]2(.mu.-H)2. Catalytic deuterium exchange on diphenylsilane and x-ray structure of [[(Me2CH)2PCH2CH2P(CHMe2)2]Rh]2(.mu.-H)(.mu.-.eta.2-HSiPh2) Kinetics of the formation of cobalt-rhodium heptacarbonyl (Benzyne)chromium tricarbonyl. Preparation and structure of Ru3(CO)9{.mu.3-P[C6H5Cr(CO)3]}[.mu.3-C6H4Cr(CO)3] and Ru3(CO)7(.mu.3-C6H4){.mu.-PPh[C6H5Cr(CO)3]}2 Reactions of [CpRuOMe]2. 7. Intramolecular transformation of a RuOCH3 unit into a Ru(CO)H unit: crystal and molecular structure of CpRu(.mu.-H)2(.mu.-CO)RuCp* Iron-sulfur interactions within azathiaferrocenophanes. Synthesis and electrochemistry of azathiaferrocenophanes and their acyclic analogs Binding of .pi.-acid ligands in diiridium and rhodium-iridium iodo complexes, including rare examples of ethylene coordination in a "a-frame" compounds. Structure of [Ir2I2(CO)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.CH2Cl2 Unusual proton NMR properties of tungsten(II) tris(pyrazolyl)borate hydride complexes Synthesis, reactivity, and ligand dynamics of Ru3(CO)9(.mu.-CO)(.mu.3-.eta.2-alkyne) compounds Cycloaddition reactions of transition-metal 2-alkynyl complexes with a disulfur monoxide source. Transition metal-mediated synthesis of five-membered ring thiosulfinate esters Bis(phenol) adduct of CpRu(.eta.5-oxocyclohexadienyl), a doubly symmetrical hydrogen-bridged ruthenium complex Mechanistic studies on metal to ligand hydrogen transfer in the thermal reactions of H(.mu.-H)Os3(CO)10(CNR): evidence for proton barrier tunneling in a metal to ligand hydrogen transfer Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3) Solution calorimetric, equilibrium, and synthetic studies of oxidative addition/reductive elimination of cyclopentadiene derivatives, C5R5H (R = H, Me, indenyl), to/from the metal complexes M(CO)3(RCN)3/(*5-C5R5)M(CO)3H (M = chromium, molybdenum, tungsten) Synthesis and structure of new molybdenum .pi.-allyl complexes: unexpected hydrolysis of tris(3,5-dimethyl-1-pyrazolyl)phospine oxide Nature of the silicon-nitrogen bond in silatranes Synthesis and reaction chemistry of new .eta.5-cyclopentadienylruthenium(II) amine and amide complexes Stabilization of .beta. positive charge by silicon, germanium, or tin New compounds of zirconium(II) and hafnium(II): synthesis and x-ray crystal structures of novel dimers of formula M2X4(.eta.6-C6H5PMe2)2(PMe2Ph)2 Oxidative-addition reactions of alkyl chlorides with chlorobis(cyclooctene)rhodium(I) and the bis(oxazolinyl)pyridine ligand: formation of stable (chloromethyl)rhodium(III) complexes and their reactions Reactions of tertiary amines with trinuclear clusters. 3. Reactions of N-methylpyrrolidine with Ru3(CO)12 and Os3(CO)10(CH3CN)2 Cycloaddition and other reactions of silenes with .alpha.,.beta.-unsaturated esters Potential energy surfaces for methyl migration in tetracarbonyl(methyl)cobalt(I) and dicarbonylcyclopentadienyl(methyl)iron(II) Synthesis of the prototype of the trans diacyl complex of platinum by intramolecular carbon monoxide transfer in an alkyl .alpha.-ketoacyl complex. Crystal structures of trans-Pt(Et)(COCOPh)(PPh3)2 and trans-Pt(COEt)(COPh)(PPh3)2 Organometallic nitrosyl chemistry. 43. Synthesis and characterization of chiral molybdenum and tungsten neutral complexes containing .eta.2-benzyl ligands Synthesis and reactivity of rhenocene derivatives Cu[P(C6H5)3]2B6H9Fe(CO)4: rational synthesis of a heterobimetallaborane from B6H10 (.eta.1-Acyl)titanium complexes prepared by the carbonylation of 1-oxa-5-titanacyclopentanes Characterization of the heterobimetallic .mu.-(.eta.1-C:.eta.2-O,O') carbon dioxide complexes (.eta.5-C5H5)(CO)2MCO2M'(Cl)(.eta.5-C5H5)2 (M = iron, ruthenium; M' = titanium, zirconium) Attempted synthesis of 1,3,5-triphenyl-2,4,9-trithia-1,3,5-triplumbaadamantane. Decomposition of organolead iodides Oxidative addition of carboxylic acid anhydrides to rhodium(I) phosphine complexes to produce novel rhodium(III) acyl derivatives Rhodium and cobalt carbonyl clusters Rh4(CO)12, Co2Rh2(CO)12, and Co3Rh(CO)12 as effective catalysts for hydrosilylation of isoprene, cyclohexanone, and cyclohexenone Laser desorption Fourier transform mass spectrometric analysis of organoactinides: uranium and thorium polypyrazolylborates Synthesis of ruthenium amide complexes by nucleophilic attack on ortho-metalated imine ligands (E,E)-(.eta.6:.eta.6-1,4-diphenyl-1,3-butadiene)bis(tricarbonylchromium) dianion. Study of its chemistry and reactivity Electron transfer between metal cluster complexes: reaction of the dianions M3(CO)112- with the dodecacarbonyltrimetal clusters M3(CO)12 (M = iron, ruthenium, osmium) Evidence for the activation of thietanes to ring opening by nucleophiles through bridging coordination Reaction of (.eta.5-pentadienyl)tricarbonylmanganese with secondary amines. Synthesis and characterization of (1-amino-.eta.3-pentenyl)tricarbonylmanganese complexes and their phosphine or tetracarbonyl derivatives Synthesis and structural characterization of the compounds [WCoAu(.mu.3-CC6H4Me-4)(CO)2(PPh3)(.eta.5-C5Me5)(.eta.6-C2B10H10Me2)] and [MoCo(.mu.-CC6H4Me-4)(CO)2(.eta.4-C4Me4)(.eta.6-C2B10H10Me2)] and studies on related mixed-metal complexes Novel pathway of a molybdenum-mediated cyclization reaction The transformation of heteroatom substituted alkynes into substituted vinylidene ligands accompanied by carbonyl insertion Convenient synthesis of cationic (.eta.3-allyl)palladium complexes. Preparative and stereochemical aspects Triorganotin compounds, [2-(methoxycarbonyl)-1,4-cyclohexadien-1-yl]dimethyltin halides: intra- and intermolecular unfolding of an inner tetrahedron to distorted trigonal bipyramids (X = Cl, Br, I) and a distorted octahedron (X = F) Group- and electron-transfer reactions of tetracarbonylferrate(2-) Competition between intramolecular oxidative addition and ortho metalation in organoplatinum(II) compounds: activation of aryl-halogen bonds (Phosphinomethyl)aluminum compounds: the role of coligands and x-ray structure determinations of the heterocycles (TMEDA)LiClAlMe2C(SiMe3)2PMe2 and (Me)(Cl)AlC(SiMe3)2PMe2SiMe2C(SiMe3)PMe2 Silicon-carbon unsaturated compounds. 31. Photochemical behavior of 1,1- and 1,2-dinaphthyltetramethyldisilanes Reactions of molecular hydrogen ruthenium complexes [RuH(.eta.2-H2)P4]BF4 with alkynes: preparation and crystal structure of the [Ru{.eta.3-(p-tolyl)C3CH(p-tolyl)}{PhP(OEt)2}4]BPh4 derivative Reduction of molybdenum imido-alkylidene complexes in the presence of olefins to give molybdenum(IV) complexes

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