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Structure and bonding of ruthenium complex cis-[Ru(bpy)2(CO)-(C(O)OCH3)](B(C6H5)4).cntdot.CH3CN (bpy = 2,2'-bipyridine)
Pentamethylcyclopentadienyl ligand activation in a cationic zirconocene complex: formation of an unusual pendant allyl ligand with 1,3-butadiene
Cis-trans isomerization and structure of dimeric [Me2Ga(.mu.-NH-tert-Bu)]2
Substituent heteroatom effects on the chemistry of triiron alkyne clusters derived from [Fe3(CO)9CCER]-: E = O versus E = S
.beta.-Hydrogen abstraction by thiyl radicals
Comparison of the dynamics and thermodynamics of the redox-promoted carbonylation of (.eta.-Cp)(CO)(L)FeMe in methylene chloride and acetonitrile. Applications of the quantitative analysis of ligand effects (QALE)
Dimesitylneopentylgermene, a new stable germene
Formation and reactions of a dirhodium complex incorporating a secondary phosphine. Intramolecular proton transfer, CNR addition, and conversion to the trinuclear cluster (.eta.-C5H5)2Rh2Ir(.mu.-PPh2)(CO)2(CF3C2CF3)
Reaction chemistry between molybdenum complex CpMo(CO)2(.eta.3-2-vinylallyl) and electrophiles: new carbon-carbon bond formation through molybdenum .eta.4-trimethylenemethane cationic intermediates
Two-dimensional carbon-13-tin-119 correlation: a new NMR tool for organotin chemistry
Paramagnetic decamethylbimetallocenes. [Erratum to document cited in CA116(21):214682m]
Tailored synthesis of hydrocarbon chains via carbon-carbon coupling reactions of diynes and alkynes on the square face of a ruthenium Ru4P cluster
New 2,4,6-triisopropylphenyl-substituted disilenes
Synthesis and structure of the nickel cluster cation [Ni3(.mu.3-Cl)(.mu.3-CO)(.mu.-Ph2PCH2PPh2)3]+
Identification of a surface organometallic species anchored on a thiourea-functionalized silica xerogel. Crystal structure of the model ruthenium compound [(.mu.-H)Ru3{.mu.3-SC(NHPr)NPh}(CO)9]
Ab initio molecular orbital study on rhodium(I)-catalyzed isomerization of allylic amines to enamines
Masthead
Neopentyl-based aminoalanes. Syntheses and molecular structures of [Neo2Al-N(H)R]2 (Neo = neopentyl (CH2CMe3); R = adamantyl, t-Bu, Ph(i-Pr)2, Ph' (2-biphenyl))
Synthesis, structure and reactivity properties of (.eta.5-C5H5)Ru[(C2F5)2PCH2CH2P(C2F5)2]X complexes: new electrophilic analogs to (.eta.5-C5H5)Ru(CO)2X systems
Cationic lanthanide alkyl complexes. Evidence for an unprecedented tetraphenylborate coordination mode in La(C5Me5){CH(SiMe3)2}BPh4
Silicon-carbon unsaturated compounds. 37. Thermal behavior of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)silacyclopropene. [Erratum to document cited in CA116(9):83751h]
Binuclear alkyl complexes: unusual ethylene adducts and facile carbon-hydrogen activation of a methyl group by an adjacent metal
Half-open titanocene chemistry: coupling reactions of pentadienyl ligands with carbon-nitrogen and carbon-oxygen multiple bonds
Ring opening and carbonylation of 3,3-dimethylthietane ligands in ruthenium carbonyl cluster complexes
Reactions of 2-lithio-1,1,3,3,5,5-hexamethyl-1,3,5-trisilacyclohexane with benzaldehyde, benzoyl chloride, and benzonitrile
Reactions of 2-furyl, 2-thienyl, and N-methyl-2-pyrrolyl mercurials with [Et3NH][(.mu.-CO)(.mu.-RS)Fe2(CO)6] complexes. Synthesis of Fe2(CO)6 complexes with bridging .eta.1:.eta.2-furyl and thienyl ligands
Comparative study of the reactions of diazomethane with .mu.3-imidoyl and .mu.3-butyne trinuclear clusters
Synthesis and x-ray structural characterization of Mg(2,4,6-R3C6H2)2(THF)2 (R = Me, iso-Pr) and the three-coordinate magnesiate species [Li(THF)0.6(Et2O)0.4][Mg(2,4,6-iso-Pr3C6H2)3]
The benzo[b]thiophene (BT) rhenium complexes Cp'(CO)2Re(BT): models for BT adsorption on hydrodesulfurization catalysts
Synthesis and characterization of novel organogallium-phosphorus compounds: x-ray crystal structures of [cyclic] Ph2GaP(SiMe3)2Ga(Ph)2Cl, Ph2(Cl)Ga.cntdot.P(SiMe3)3, and Ph3Ga.cntdot.P(SiMe3)3
Organometallic oxides: oxidation of [(.eta.-C5Me5)Mo(CO)2]2 with O2 to form syn-[(.eta.-C5Me5)MoCl]2(.mu.-Cl)2(.mu.-O), syn-[(.eta.-C5Me5)MoCl]2(.mu.-Cl)(.mu.-CO3H)(.mu.-O), and [C5Me5O][(.eta.-C5Me5)Mo6O18]
Interaction of iron ethynyl and ethynediyl complexes with Cp2Ni2(CO)2: formation of tri- and tetranuclear adducts with a multiply bridging C2H ligand
Oxygenation under UV light of allylsilanes catalyzed by palladium(II) and of (.eta.3-allyl)palladium complexes: a mechanistic approach
Phase-transfer photolysis of metal hexacarbonyls
Selective formation of cis-(HMe2Si)2Pt(PEt3)2 from HMe2SiSiMe2H and Pt(PEt3)3 and its reactivities relevant to generation of (silylene)platinum species thereof
Weak Rh.rarw.H-C interactions. Molecular structure of rhodium complex [trans-Rh(CO)(8-methylquinoline)(PPh3)2]BF4
Synthesis and electronic and molecular structures of .eta.-cycloheptatrienyl .eta.-cyclopentadienyl derivatives of vanadium, niobium, and tantalum: photoelectron spectroscopic, electrochemical, and x-ray crystallographic study
Dihydrogen: a better ligand than water? IR and x-ray evidence for aquo coordination in W(CO)3(PR3)2(H2O), thermodynamics of H2O binding versus .eta.2-H2 binding and H2O/D2 isotopic exchange. Implications for the biological activation of hydrogen
Carbon-carbon and carbon-oxygen bond formation from the reaction of platinum(II) with bicyclo[4.1.0]hept-2-ene and related derivatives
Linear trimerization of phenylethyne: homogeneous catalysis with triangulo-Co3(.mu.3-H)(.mu.2-CO)3(PMe3)6
Kinetics and mechanism of the thermal decomposition of 1,1-dimethylgermetane
Geometrical and electronic structures of .pi.-conjugated silicon ring polymers
Synthesis, structure, and reactivity of allene complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+
Tungsten(IV) alkyls and .eta.2-acyls. Carbonyl insertion and ligand substitution reactions of the tungsten dication CpW(CO)2(NCMe)2Me2+ and related complexes
Structure of Os(CO)4(C2H4), an osmacyclopropane
Hydrogenation of benzylideneacetone catalyzed by OsHCl(CO)(PR3)2 (PR3 = P-iso-Pr3, PMe-tert-Bu2): new roles of dihydrogen complexes in homogeneous catalytic hydrogenation
Regiospecific mono-transmetalation of 4-stanna-3a,4,4a,8-tetrahydro-4,4,8,8-tetramethyl-s-indacenes
Understanding electronic effects in organometallic complexes. Influence of methyl substitution on hafnocene dihalides. [Erratum to document cited in CA115(1):8967j]
Observation of rhodocenium and substituted-rhodocenium ions and their neutral counterparts by mass spectrometry
.mu.3-.eta.2-Acyl and .mu.-alkylidene complexes of a molybdenum-triosmium cluster. Crystal structure of CpMoOs3(CO)9(.mu.-H)(.mu.-O)(.mu.-CHCH2Tol)
Synthesis and characterization of the electron-rich iron hydride HFe(CO)2(P(OPh)3)2- and its ligand-based redox substitution with thiolates
Fulvalene derivatives of titanium: x-ray structures of [(TiCl2)2(.mu.-O)(.mu.-.eta.5:.eta.5-C10H8)] and [{Ti(CH2C6H5)3}2(.mu.-.eta.5:.eta.5-C10H8)]
Double metalation and iron-osmium bonding involving ferrocenyl moieties on clusters. Crystal and molecular structures of H2Os3(CO)8[(.eta.-C5H4)Fe(.eta.-C5H3PPr2-iso)] and H2Os3(CO)8[(.eta.-C5H4)Fe(.eta.-C5H3PFcEt)]
Syntheses, kinetics, and mechanism of ligand substitution reactions of 17-electron half-open chromocene carbonyl complexes
Fluorine-19 NMR studies of the reaction of octaphenylcyclotetrasilane with triflic acid
Carbon-13 NMR spectroscopic and EHMO study of slowed tripodal rotation in [(benzyl)Cr(CO)3]+ and (fulvene)Cr(CO)3 systems: metal-stabilized nonplanar cations
Incorporation of trialkylsilyl and trialkylstannyl groups into ruthenium carbonyl clusters. Carbonyl substitution versus trialkylsilane or trialkylstannane elimination in these clusters
Structure of the [1.1]metallocenophanes of iron and ruthenium. Single-crystal x-ray diffraction analysis of (C5H4-CH2-C5H4)2Fe2, (C5H4-CH2-C5H4)2FeRu, and (C5H4-CH2-C5H4)2Ru2
Synthesis and characterization of an organoyttrium dimer produced via an Arbuzov dealkylation reaction
Synthesis and molecular structure of Fe2(CO)8[.mu.-CuP(tert-Bu)3]2: a distorted Fe2Cu2 core with a doubly Cu(PR3)-bridged iron-iron single bond
Transition metal stannyl complexes. 6. Chelate-assisted oxidative addition of tin-carbon bonds to an iron center
Molecular orbital study of the anionic carbonyl cluster Fe2Co(CO)9CCO- and the products of its reactions with phosphines
Enthalpies of reaction of (benzylideneacetone)iron tricarbonyl, (BDA)Fe(CO)3, with phosphine ligands. Thermodynamic insights into iron chemistry
Mercuration of a ruthenocene. Synthesis, characterization, and halogenation of [[C5(HgOAc)5](C5Me5)Ru]
Influence of the .pi.-conjugated carbon moiety on the electronic structure of polymeric organosilicon systems
Photoelectron spectroscopy of f-element organometallic complexes. 8. DV-X.alpha. and gas-phase UV photoelectron spectroscopic investigation of the electronic structure of tris(.eta.5-cyclopentadienyl)uranium(IV) complexes
Applications of two-dimensional phosphorus-31 CP/MAS NMR techniques for studying metal phosphine complexes in the solid state
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