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Rhodium-catalyzed reaction of N,N-acetals with a hydrosilane and carbon monoxide
(Aryne)- and (alkyne)metallocene derived dimetallic zirconium/aluminum complexes containing planar-tetracoordinate carbon
New silane-induced carbonyl activation in [(.eta.5-H3CC5H4)Mn(CO)2.cntdot.THF]: formation of the cyclic bis(.mu.-carbyne) complex [cyclic] (.eta.5-H3CC5H4)(CO)Mn(.mu.-COSiH(t-Bu)2)2Mn(CO)(.eta.5-H3CC5H4) and the carbon-carbon coupling reaction of the siloxy-carbyne ligands
Comparative photochemistry of ring-substituted half-sandwich tetracarbonylvanadium complexes in low-temperature matrices at ca. 12 K
Synthesis and structure of phosphaalkenylmercury compounds
Coordination chemistry of perhalogenated cyclopentadienes and alkynes. 8. Pentakis(dimethylsilyl)cymantrene
Mechanistic study of hydrogen activation by cationic dinuclear (.mu.-sulfido)molybdenum complexes. [Erratum to document cited in CA117(5):48806d]
Metal transfer and double acyl formation in the reaction of ((trimethylsilyl)ethynyl)(Fischer carbene)metal complexes with dicobalt octacarbonyl
Stereochemically matched (and mismatched) bisphosphine ligands: DIOP-DIPAMP hybrids
1,3-Dipolar cycloaddition reactions to the C:XM fragment. 7. The reaction of Ru(CO)3(iso-Pr-DAB) with dimethyl acetylenedicarboxylate. X-ray crystal structure of the protonated initial bicyclo[2.2.1] adduct
Carbon-carbon bond formation in cationic aryl-olefin-platinum(II) complexes
Structure and bonding in Group 4 metallocene acetylide and metallacyclopentadiene complexes
Application of molecular mechanics (MMX) calculations to an investigation of the conformations of coordinated triphenylphosphine in organometallic compounds of the types (.eta.6-C6R6)Cr(CO)2PPh3 and (.eta.5-C5H5)Fe(CO)(PPh3)R' (R = H, Me; R' = H, alkyl, acyl)
Hypervalent monoorgano- and diorganotin(IV) fluoride complexes: a fluorine-19 and tin-119 study of inter- and intramolecular dynamics in solution
Synthesis of Os3(CO)10(CNR)(NCMe) and its reaction with propynoic acid
Reinvestigation of the electrochemical behavior of the Co2(CO)6(ethynylestradiol) complex. Evidence of efficient recombination of the electrogenerated fragments
Isodicyclopentadienes and related molecules. 57. Stereocontrolled synthesis of sterically crowded titanocenes of high enantiomeric purity by electrophilic capture of C-silylated ligands with configurational inversion
Regioselective hydroformylation of cyclic vinyl and allyl ethers with rhodium catalysts. Crucial influence of the size of the phosphorus cocatalyst
Hydroxylation of aromatics with hydrogen peroxide catalyzed by cationic complexes of platinum(II). Evidence for the intermolecular oxidation of platinum aryls
Transformations of chiral (.eta.6-arene)chromium complexes in organic synthesis: diastereoselective 1,4-addition reactions of organocopper reagents to (ortho-substituted-phenyl (E)-enone)chromium complexes
Masthead
Ring opening of strained-ring heterocycles containing nitrogen by an osmium cluster complex
Formation of [CH4-Fe]q (q = -1, 0, +1) complexes and oxidative addition of methane to Feq atoms. A qualitative molecular orbital study
Photochemistry of 1,2-di-tert-butyl-1,1,2,2-tetraphenyldisilane, a clean, direct source of arylalkylsilyl radicals
Carbonylation of the ruthenium-methyl bond of Ru(Me)(I)(CO)2(i-Pr-N:CHCH:N-i-Pr) catalyzed by Ru(CO)4(PR3), ZnCl2, and H+
Electronic structure of triple-decker sandwich complexes with P6 middle rings. Synthesis and x-ray structure determination of bis(.eta.5-1,3-di-tert-butylcyclopentadienyl)(.mu.-.eta.6:.eta.6-hexaphosphorin)diniobium
Silylene-bridged ruthenium dimers via reactions of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2 with silanes. Structure of {[(.eta.5-C5Me5)Ru]2(.mu.-SiPhOMe)(.mu.-OMe)(.mu.-H)}
Structural and spectroscopic studies of cation-anion interactions in pentacoordinate organotin compounds
Reactions of thioallenes with triiron dodecacarbonyl: a route to thioallyl-bridged diiron hexacarbonyl complexes
Bis(tetramethylthiophene)ruthenium(0) and its iron tetracarbonyl adduct
Synthesis and properties of ortho-formylaryl complexes of palladium(II). Some examples of organometallic reactions of water soluble arylpalladium(II) complexes. Unusual palladium-assisted rearrangement of HC(O)C6H2(OMe)3-3,4,5 to HC(O)C6H2(OMe)3-2,3,4. X-ray structure of [Pd{C6H(CHO)-6-(OMe)3-2,3,4}Cl(bpy)]
NMR studies of (amido)cuprates
Structure of dilithio-(E)-1,4-bis(trimethylsilyl)but-2-ene by x-ray crystallography and 1H-7Li HOESY
ansa-Metallocene derivatives. 26. Biphenyl-bridged metallocenes that are chiral, configurationally stable, and free of diastereomers
Synthesis and characterization of five-coordinate platinum [PtCl(L)(N-N)(olefin)]+ complexes. Molecular structure of [PtCl(pyridine)(2,9-dimethyl-1,10-phenanthroline)(ethylene)] (CF3SO3)
Tetraazamacrocyclic derivatives of arsenic: HcyclenAs, HcyclenAs.GaMe3, and HcyclamAs
Nature of the stabilization of a carbenium ion adjacent to two organometallic groups. [Mo2Cp2(CO)4(.mu.-FcCHC:C(CH2)2CH3]+, BF4-: x-ray structure and NMR dynamic investigation
Regiospecific C:C protection and cyclopropanation of dienes both assisted by [(.eta.5-C5Me5)Fe(CO)2]+
Metalloradical reactions of rhodium(II) porphyrins with acrylates: reduction, coupling, and photopromoted polymerization
Open and half-open manganocene chemistry: more associated salts
Transition metal polyhydride complexes. 5. Complexes with a cyclopentadienyl ligand
Rare example of a monomeric aryllithium complex. X-ray crystal structure of (2,4,6-triphenylphenyl)lithium-bis(diethyl ether)
Tetramesitylgermasilene: the first relatively stable germasilene and its rearrangement to a silylgermylene
Reactions of acyl-substituted molybdenum carbyne complexes under photooxidative and thermal conditions. Formation of cyclopentenones and oxymetallacycles
Synthesis, molecular structure and reactivity of the octahedral iridium(III) compound [IrH(.eta.1,.eta.3-C8H12)(dppm)] [dppm = bis(diphenylphosphino)methane]
Unprecedented trimetallic cluster with an in-plane .mu.3-hydride ligand. X-ray crystal structure of [Mo2(CO)8(.mu.-dppm)(.mu.3-H)(.mu.-AuPPh3)]
Preparation of novel alkylated ruthenium .alpha.-diimine complexes: reactivity toward carbon monoxide and phosphines
Silaheterocycles. 21. Silene to silene rearrangement: intramolecular [1,3]-migration of alkoxy groups
Synthesis and photochemistry of the aqueous-soluble (.eta.5-C5H4CH2CH2NH3+)2Mo2(CO)6 complex. Generation of 19-electron complexes in aqueous solution
Reactions of monoazadienes with metal carbonyl complexes. 14. Pseudo-allyl complexes from monoazadienes and cobalt carbonyl [Co2(CO)8] by activation of dihydrogen under mild conditions
Volumes of activation for solvent displacement reactions on pentacarbonylchromium(0). Comparison of data for pure and mixed solvents
A deceptively simple case of selective hydrogenation of phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complex
Mercuration of Schiff bases of substituted benzylideneanilines
Stereochemistry of the thermal decomposition of [2-(acyloxy)alkyl]triorganostannanes
(.eta.1-Cp)Tc(NAr)3: synthesis and structure
Kinetic study of additions of dialkylmagnesium compounds to a cyclopropene
Photochemical synthesis of trinuclear cluster compounds of osmium and a Group 6 metal atom. Structures of (OC)5M[Os(CO)3(PMe3)]2 (M = chromium, tungsten), (OC)5Mo{Os(CO)3[P(OMe)3]}2/[(MeO)3P](OC)4OsMo(CO)5 (1/1), and (OC)4W[(.mu.-H)Os(CO)3(PMe3)]2
Catalytic thermal carbon-hydrogen activation with manganese complexes: evidence for .eta.2-H2 coordination in a neutral manganese complex and its role in carbon-hydrogen activation
Pd6(.mu.3-CO)4(PMe3)7: the first octahedral hexapalladium cluster core
Organometalloidal derivatives of the transition metals. 31. Thermal and photochemical properties of [(1- and 2-heptamethyltrisilyl)methyl]iron complexes (.eta.5-L)Fe(CO)2CH2Si3Me7 (L = C5H5, C5Me5, C9H7. [Erratum to document cited in CA117(1):8171m]
Trapping of a phosphenium ion and an activated alkyne into the metal-nitrogen bond of Li[(.eta.2-cyclenP)Mo(CO)4]. Insertion reactions?
Clusters as ligands. Stabilization of a cadmium-cobalt Cd3Co core in [.mu.3-Co(CO)3]Cd3{.mu.-[(CO)9Co3(.mu.3-CCO2)]}3(THF)3
Stable bis(silyl)palladium complexes: synthesis, structure, and bis-silylation of acetylenes
Alkylidyne (carbaborane) complexes of the Group 6 metals. 9. The closo to hyper-closo transformations in a tungstacarborane cage system: crystal structure of [NEt4][W2(.mu.-CC6H4Me-4)(CO)2(.eta.5-7,8-Me2-7,8-C2B9H9)[.eta.6-7,8-Me2-7,8-C2B9H8-10-(CH2C6H4Me-4)]]
Diastereoselective carbene insertions into platinum-halogen bonds. Crystal structure of [PtCl(R-CHClCO2Et)(R,R-diop)]
Nucleophilic ring opening of bridging thietane ligands in trirhenium carbonyl cluster complexes
Transition-metal-catalyzed decomposition of silylated diazoacetic esters: influence of silicon substituents, catalyst, and solvent on product formation
Intramolecular redox chemistry of molecules with alkyne and CCo3 cluster functionalities: electronic interaction and structural isomerism in reduced clusters with multiple redox centers
Enantiomerically pure copper(I) and zinc(II) complexes of a novel C3-symmetric polypyrazole ligand. [Erratum to document cited in CA117(12):123357p]
Insertion of alkynes with electron-withdrawing substituents into a rhenium-rhenium bond. Evidence for an intramolecular insertion with a trans stereochemistry
Investigation of the applicability of molecular mechanics (MMX) calculations to a conformational investigation of organometallic compounds of the types (.eta.5-C5H5)Fe(CO)2R, (.eta.5-C5H5)Fe(CO)2C(O)R, and (.eta.5-C5H5)Fe(CO)(PPh3)R (R = H, alkyl, acyl)
Synthesis of thermochromic dibismuthines with nonthermochromic distibine analogs
Deprotonation of rhenium terminal acetylide complexes (.eta.5-C5R5)Re(NO)(PPh3)(C.tplbond.CH): generation and reactivity of rhenium/lithium C2 complexes
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes
Rearrangement barriers in doubly bonded germanium compounds
Synthesis and reactivity of cyclohexadienyl- and o-xylylenetricarbonylmanganese complexes obtained from the deprotonation of [Mn(.eta.6-arene)(CO)3]+ salts
Formation of a highly-ordered polymeric, supersandwich metallocene: The first x-ray crystal structure of a base-free lithium cyclopentadienide, [[.mu.-.eta.5:.eta.5-C5H4(SiMe3)]Li]n
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