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The ions MCp2+ (M = scandium, lanthanum): significantly bent sandwich species
Palladium(II)-catalyzed exchange and isomerization reactions. 15. Kinetics and stereochemistry of the isomerization of 2-(methyl-d3)-4-methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-ol in aqueous solution catalyzed by PdCl42- at high chloride concentrations
Reactions of ruthenium complex [Cp*RuOMe]2. 10. Synthesis, structure, and transformations of [Cp*Ru(.mu.-.eta.3-O(CH2)2CH:CH2)]2, an alkoxide-bridged dimer destabilized by internal .pi.-coordination
2-Hetero-1.lambda.5,3.lambda.5-diphosphabenzenes as ligands in molybdenum complexes
Topological reorganization of gallium-sulfido clusters
Synthesis, structure, and absolute configuration of chiral, pseudooctahedral perfluoroalkyl-substituted dimethylphosphonate complexes
Reactions of metal-metal and metal-carbon multiple bonds with 2H-azirines, 1,3-dipolar reagents. Structures of Cp2M2(CO)4(NC(Ar)=CMe2) (Ar = aryl; M = molybdenum tungsten) and (CO)5W-N(=CPh(OMe))(C(Ph)=CMe2)
Fluxionality of iron complex Fe2(CO)4(.eta.-C5H5)2 revisited
Triangulo cluster molecules of cobalt(0) and nickel(0) containing trimethylphosphine and carbonyl ligands: syntheses, properties, and x-ray structures
Organometallic dioxotungsten(VI) complexes of the hydrotris(3,5-dimethyl-1-pyrazolyl)borate ligand
Pentadienyl-metal-phosphine chemistry. 24. Thiapentadienyl-iridium-phosphine chemistry. Synthesis of sulfur-containing iridacycles via carbon-hydrogen bond activation
Ferrocene derivatives. 27. Ferrocenyldimethylphosphine
Synthesis and characterization of new chromium-centered radicals of the type {.eta.3-tris(pyrazolyl)borato}Cr(CO)2L (L = CO, PMe3): EPR spectra of organochromium and -molybdenum compounds undergoing subtle Jahn-Teller distortions
Laser flash photolysis of octaisopropylcyclotetragermane. Generation of digermenes and germylenes
A highly efficient route to ferrocene derivatives containing four-carbon heteroannular bridges via a novel cyclization reaction
Synthesis and characterization of chiral (-)-menthyltin(IV) compounds. X-ray structure of tert-butyl-8-(dimethylamino)naphthyl-(-)-menthyltin hydride
Binuclear cyclopentadienyl carbonyl complexes of molybdenum(I) with bidentate phosphorus bridging ligands: synthesis and reactions leading to new dimolybdenum(II) complexes
A stable compound with a formal tin-carbon double bond: the bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannene
Novel binuclear bis(dimethylphosphino)methane-bridged complexes of rhodium containing two and three alkyne molecules
Studies on carbon-hydrogen activation. 7. Carbon-hydrogen activation of ethene by non-cyclopentadienyl-containing iridium complexes. Supporting role of iPr2PCH2CH2OMe as phosphine ligand
Synthesis and properties of tricarbonyl(exo-cyclopentadienyl-.eta.5-cyclohexadienyl)manganese
Synthesis and properties of organometallic rings and macrocycles containing ferrocene, silicon, and unsaturated hydrocarbon units: x-ray crystal structures of the novel ferrocenophanes Fe(.eta.-C5H4)2(SiMe2)2(CH:CH) and trans,trans-Fe(.eta.-C5H4)2(SiMe2)2(CH2CH:CHCH2)2
Trinuclear and dinuclear fluorinated ferroles by cluster rearrangement and degradation reactions
Homogeneous catalysis. Titanium complex [Ti(Cp)2(CF3SO3)2] and zirconium complex [Zr(Cp)2(CF3SO3)2THF], efficient catalysts for the Diels-Alder reaction
Unusual low-valent dirhodium complexes bridged by bis(dimethylphosphino)methane ligands
Synthesis, characterization, and structure of acetylenic gallium dialkylphosphides having the formula [(tert-Bu)(Me3SiC.tplbond.C)GaPR2]2 (R = Et, iso-Pr, tert-Bu)
From .sigma.- to .pi.-bonding: crystal structures of (pentamethylcyclopentadienyl)triiodostannane and dichloro(pentamethylcyclopentadienyl)stibine
Electrochemistry of organosilicon compounds. 3. Synthesis of poly(disilanylene)ethylenes by electrolysis of bis(chlorosilyl)ethanes
Synthesis and reactivity of cyclic phosphetanes. Oligomerization, quaternization, and complexation with platinum(II)
Living cyclopolymerization of diethyl dipropargylmalonate by Mo(CH-t-Bu)(NAr)[OCMe(CF3)2]2 in dimethoxyethane
Practical synthesis of tris(trimethylsilyl)methyl bromide and its conversion to the corresponding Grignard reagent and (tris(trimethylsilyl)methyl)lithium
Enantiomerically pure copper(I) and zinc(II) complexes of a novel C3-symmetric polypyrazole ligand
Cationic and neutral 50-electron triruthenium carbonyl clusters containing three bridging diphenylphosphido ligands
Synthesis and characterization of volatile trifluoromethyl alkyl tellurides
Secondary bonding in organobismuth compounds. Comparison of the structures of 2,2',5,5'-tetramethyl-1,1'-dibismaferrocene and 2,2',5,5'-tetramethylbibismole
Synthesis and x-ray characterization of the neutral organometallic gold cluster [Au10(C6F5)4(PPh3)5]
Preparation and properties of (S,S)-[Ti((R,R)-cyclacene)Cl2], a chiral strapped bent metallocene
Stereodynamics of 6-exo-phenylcyclohexadienyl complexes of manganese and rhenium
Alkyl group substitution by oxime-bound palladium(II) (the Shaw reaction): alkyl group selectivity and deuterium isotope effects
Effect of an nitrogen-nitrogen chelate ligand on the insertion reactions of carbon monoxide into a manganese-alkyl bond
Electron-donor ability of the unsaturated dimanganese hydrides [Mn2(.mu.-X)(.mu.-H)(CO)6(.mu.-dppm)] (X = H, AuPPh3; dppm = Ph2PCH2PPh2). X-ray crystal structures of [Mn2[.mu.-Ag(ClO4)PPh3](.mu.-H)2(CO)6(.mu.-dppm)] and [Mn2(.mu.-AuPPh3)2(.mu.-H)(CO)6(.mu.-dppm)][PF6].cntdot.C7H8
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Preparation of doubly acetylide-bridged binuclear platinum-platinum and platinum-palladium complexes. Structures of [[(dppe)Pt(C.tplbond.CPh)2]Pt(C6F5)2] and (PMePh3)2[(C6F5)2Pt(.mu.-C.tplbond.CPh)2Pt(C6F5)2]
Controlled and selective introduction of a Cp*Ru+ (Cp* = C5Me5) fragment to the 17.alpha.-substituent of 17.alpha.-phenylestradiol
Syntheses and molecular structures of hexasilylbenzenes and disilylacetylenes
Unexpected substitution reactions of alkoxy-, acyloxy-, and chlorobis(.eta.5-cyclopentadienyl)methyltitanium(IV) complexes with acids
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